Enlarging the molecular size of zinc phthalocyanine (Pc) dyes three dimensionally with 2,6-diphenylphenoxy substituents significantly reduced the aggregation of the dyes on a TiO(2) surface. As a result, the incident photon-to-current conversion efficiency was improved not only in the Q band but over the whole absorption range, achieving 4.6% energy conversion efficiency under one-sun conditions. Electron lifetime measurements indicated that these Pc dyes do not enhance charge recombination, encouraging further development of Pc.
Gallium oxide (Ga2O3) nanowires were grown on fused quartz and Si substrates by a vapor transport method of heating gallium metal at 750−1100 °C in a tube of the horizontal furnace. The obtained white colored product has shown to be the Ga2O3 nanowires with average diameters ranging from 30 to 80 nm. The optical transmittance spectra indicated that the bandgap energy of Ga2O3 nanowire increases as the diameter of nanowire decreases.
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