We develop hetero-nanostructured black phosphorus/metal-organic framework hybrids formed by P-O-Co covalent bonding based on ad esigned droplet microfluidic strategy consisting of confined and ultrafast microdroplet reactions.T he resulting hybrid exhibits large capacitance (1347 Fg À1 )i nK OH electrolytes due to its large specificsurface-area (632.47 m 2 g À1 ), well-developed micro-porosity (0.38 cm 3 g À1 ), and engineered electroactivity.F urthermore, the proposed 3D printing method allows to construct allintegrated solid-state supercapacitor,w hich maintains interconnected porous network, good interfacial adhesion, and robust flexibility for short-path diffusion and excessive accommodation of ions.C onsequently,t he fabricated flexible supercapacitor delivers ultrahigh volumetric energy density of 109.8 mWh cm À3 ,l arge capacitance of 506 Fcm À3 ,a nd good long-term stability of 12000 cycles.

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We develop hetero-nanostructured black phosphorus/metal-organic framework hybrids formed by P-O-Co covalent bonding based on ad esigned droplet microfluidic strategy consisting of confined and ultrafast microdroplet reactions.T he resulting hybrid exhibits large capacitance (1347 Fg À1 )i nK OH electrolytes due to its large specificsurface-area (632.47 m 2 g À1 ), well-developed micro-porosity (0.38 cm 3 g À1 ), and engineered electroactivity.F urthermore, the proposed 3D printing method allows to construct allintegrated solid-state supercapacitor,w hich maintains interconnected porous network, good interfacial adhesion, and robust flexibility for short-path diffusion and excessive accommodation of ions.C onsequently,t he fabricated flexible supercapacitor delivers ultrahigh volumetric energy density of 109.8 mWh cm À3 ,l arge capacitance of 506 Fcm À3 ,a nd good long-term stability of 12000 cycles.

Cryptomeria fortunei Hooibrenk (Chinese cedar) is a coniferous tree from southern China that has an important function in landscaping and timber production. Lignin is one of the key components of secondary cell walls, which have a crucial role in conducting water and providing mechanical support for the upward growth of plants. It is mainly biosynthesized via the phenylpropanoid metabolic pathway, of which the molecular mechanism remains so far unresolved in C. fortunei. In order to obtain further insight into this pathway, we performed transcriptome sequencing of the C. fortunei cambial zone at 5 successive growth stages. We generated 78,673 unigenes from transcriptome data, of which 45,214 (57.47%) were successfully annotated in the non-redundant protein database (NR). A total of 8975 unigenes were identified to be significantly differentially expressed between Sample_B and Sample_A after analyzing their expression profiles. Of the differentially expressed genes (DEGs), 6817 (75.96%) and 2158 (24.04%) were up- and down-regulated, respectively. 83 DEGs were involved in phenylpropanoid metabolism, 37 DEGs that encoded v-Myb avian myeloblastosis viral oncogene homolog (MYB) transcription factor (TF), and many candidates that encoded lignin synthesizing enzymes. These findings contribute to understanding the expression pattern of C. fortunei cambial zone transcriptome. Furthermore, our results provide additional insight towards understanding the molecular mechanisms of wood formation in C. fortunei.

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