Interface degradation between mandrel and sheath can cause a decrease in insulation performance and mechanical strength of composite insulators. In this study, the interface ageing properties of cycloaliphatic epoxy resin and silicone rubber composite insulator were compared. A water diffusion test was adopted to simulate the composite insulator ageing in a hot and humid environment. A four‐electrode system was built to detect leakage current at different locations (mandrel, sheath and interface), which is an important basis for evaluating insulator performance. The ageing degree of insulator could be quantitatively characterised by leakage current change. It was found that the infiltrated moisture had a great effect on insulation performance. Based on the water absorption test result, the interface performance of two insulators was mainly influenced by their sheath sealing quality. As an auxiliary evaluation method, temperature rise during the test was recorded using an infrared camera. The experiment results showed that interface degradation was the main factor for the insulation performance decrease of silicone rubber composite insulators. However, insulation level reduction of the cycloaliphatic epoxy resin was caused by the wet sheath. In addition, a model for temperature rise of cycloaliphatic epoxy resin insulators was proposed based on good correspondence between sheath material and insulation. The model incorporated multiple processes such as ageing and heating of insulators, and it can predict the early temperature rise well.