Water Alternating Gas (WAG) approach can improve the efficiency of gas flooding. However, the precipitation damage that is induced by the gas injection may be inevitable. The precipitation pressure point test of gas injection, and the WAG parallel double-tube long-core flooding experiment under different injection conditions were systematically performed to obtain the optimum injection parameters. The variations of petrophysical properties were caused by precipitation, and its morphology was also determined by centrifugal capillary force and environmental scanning electron microscope. The precipitation pressure rised with the increase of the amount of gas injection, generally 2.0 MPa ~ 3.0 MPa higher than the bubble point pressure (Pb), and it was confirmed by X-ray energy spectrum and scanning electron microscope that the precipitation was mainly asphaltene. The optimum injection parameters for WAG were Gas–Water Ratio (GWR) of 1:1 and slug size of 0.1 HydroCarbon Pore Volume (HCPV), which benefited the recovery of low-permeability and high-permeability pipe by additional recovery of 28.5% and 17.4% respectively, while WAG process enhanced the total oil recovery by 23.4%. The pore volume and median radius of capillary pressure of all cores were both reduced with more obvious effects on conglomerate. Combined with the results of sediment saturation, it also showed the poorer the physical properties of the cores, the severer the influence of the precipitation. Overall, the WAG could greatly improve the recovery but the influence of precipitation must be considered.

Five groups of methane isotherm adsorption tests were carried out at 61 °C under a pressure range of 0-25 MPa, including four groups of pure clay minerals (illite, montmorillonite, chlorite, kaolinite, for brief they are expressed as Ill, Mont, Chl, and Kaol respectively) and a group of mixed minerals by four pure clay minerals in equal mass ratio. The experimental results showed the order of methane adsorption of pure clay minerals: Kaol > Ill > Mont > Chl. And the composition of clay minerals was obtained by XRD experiments. The result showed that the four samples were of high purity, both of which were greater than 90%. In addition, the results of low-pressure nitrogen adsorption experiments showed the order of specific surface area: Kaol > Ill > Mont > Chl, which is consistent with the order of methane adsorption. The methane adsorption is positively correlated to the specific surface area. The adsorption data was fitted to the Langmuir-Freundlich model to establish the method to calculate the adsorption of mixed minerals. The result showed that the parameters of the adsorption model of mixed clay minerals can be obtained by summing the parameters of the adsorption model of the pure minerals contained in the mixture according to their constituent mass ratio and the feasibility of this result was also verified by literature data. Overall, once the mass ratio in mixed clay minerals gets known, its theoretical adsorption can be calculated.