Yves Castanet scite author profile

A conversion of up to 100% and a selectivity for aldehyde formation of up to 95% is achieved in the Rh‐catalyzed hydroformylation of dec‐1‐ene in the two‐phase system water/alkene in the presence of partially methylated β‐cyclodextrins [Eq. (a); R = Me; acac = acetylacetonate]. These remarkable results are attributed to the formation of an alkene/cyclodextrin inclusion complex as well as to the solubility of the chemically modified cyclodextrins in both phases.

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Catalytic oxidation of α-pinene by transition metal using t-butyl hydroperoxide and hydrogen peroxide

Allal¹,

Firdoussi²,

Allaoud³

et al. 2003

Journal of Molecular Catalysis A: Chemical

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A further breakthrough in biphasic, rhodium-catalyzed hydroformylation: the use of Per(2,6-di-O-methyl)-β-cyclodextrin as inverse phase transfer catalyst

Monflier

Tilloy

Frémy

et al. 1995

Tetrahedron Letters

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Yves Castanet

Rhodium catalyzed hydroformylation of water insoluble olefins in the presence of chemically modified β-cyclodextrins: evidence for ligand-cyclodextrin interactions and effect of various parameters on the activity and the aldehydes selectivity

Molecular Recognition between Chemically Modified β‐Cyclodextrin and Dec‐1‐ene: New Prospects for Biphasic Hydroformylation of Water‐Insoluble Olefins

Catalytic oxidation of α-pinene by transition metal using t-butyl hydroperoxide and hydrogen peroxide

A further breakthrough in biphasic, rhodium-catalyzed hydroformylation: the use of Per(2,6-di-O-methyl)-β-cyclodextrin as inverse phase transfer catalyst

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