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The growth mechanism of amorphous carbon film by the liquid deposition process is still unclear. In this study, the influence of applied voltages on the surface morphology and microstructure of amorphous carbon films was investigated as well as the bonding probability at the film/substrate interface, and a new mechanism of film growth was proposed from the electrochemistry and non‐equilibrium thermodynamics viewpoints. The results showed that growth of amorphous carbon film involved the island groove morphology; more graphitic carbons are present within the film as the applied voltage increased. A coupling model of the growth mechanism including the ionization–absorption–dehydrogenation process and the chemical volume polymerization is highlighted. Copyright © 2016 John Wiley & Sons, Ltd.

The fast charging process of high-pressure gas storage cylinders is accompanied by high temperature rise, which potentially induces the failure of solid materials inside the cylinders and the underfilling of the cylinders. A two-dimensional (2D) axisymmetric model simulated the charging process of hydrogen storage cylinders with a rated working pressure of 35 MPa and a volume of 150 L. During filling, the highest temperature rise inside the cylinder occurs at the bottom part of the cylinder, and the state of charge (SOC) is 46.4% after filling. This temperature rise can be reduced by precooling the injected hydrogen, and the highest SOC can reach 95.7% after injection. The SOC in the cylinder gradually increases with a decrease in the temperature of the hydrogen injection. The maximum SOC increase is 49.3%. For safety and the SOC exceeding 90%, the hydrogen gas should be precooled to below −10 °C, and the SOC could achieve more than 90.3%. The internal structure of the hydrogen cylinder was further optimized without a precooling condition. The selected length ratios were 25%, 50%, and 75%. Compared with the initial scheme, the SOC in the optimization scheme increased by 16%, 38.7%, and 40.1%.