The structure of the title compound, C22H24N2O9S2, is described. This compound consists of a sugar ring and a heterocyclic base linked unusually by an S atom. The sugar is in a 4C1 chair conformation and forms dihedral angles of 49.54 (4) and 33.42 (5)degrees with the thiadiazole and phenyl rings, respectively. The S atom occupies an equatorial position of the sugar ring and lies 1.807 (2) A out of the corresponding mean plane.

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