With the development of electric vehicle industry, it is necessary to construct more electric vehicle charging stations to promote the popularization of electric vehicles. As photovoltaic generation owns flexible installing, convenient power supplying, and environmental protecting characteristics, it is suitable for providing power for electric vehicle charging stations and reducing a network loads. After analyzed electric vehicle charging demand, this paper proposed the designing concept of the electric system for the photovoltaic generation mix charging station, which was based on the battery charging and discharging characteristics as well as its usage. Then, the paper provided a selection of electric equipments for the charging station and an electric wiring diagram after designing the electric system. This study and design may help for promoting construction of electric vehicle charging stations, and development and popularization of electric vehicles.