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A series of oxazolidinone-based strobilurin analogues were efficiently synthesized by the reaction of 3-(2-bromomethylphenyl)oxazolidin-2-one with 1-substituted phenyl-2H-pyrazolin-3-one. Their structures were confirmed and characterized by 1 H-NMR, 13 C-NMR, elemental analysis, and mass spectroscopy. In addition, the crystal structure of the target compound 3-(2-((1-phenyl-2H-pyrazol-3-yloxy)methyl)phenyl) oxazolidin-2-one was determined by single crystal X-ray diffraction. The bioassay results of these compounds indicated that some of the oxazolidin-2-one derivatives containing N-substituted phenyl 2H-pyrazol ring exhibited potential in vivo fungicidal activities against M. grisea at the dosage of 1 g L -1. Key Words: Strobilurin fungicide, Oxazolidinone, Synthesis, X-ray diffraction, Structure-activity relationships

The new energy vehicle is a robust measure to solve the problem of global warming. However, the new energy vehicle generally has the disadvantages of short mileage and difficulty in finding public chargers. The combination of wind energy harvest and new energy vehicle can be conducive to the promotion of the new energy vehicle. This paper proposes a novel adjustable Savonius vertical axis wind turbine (SVAWT). It contains three parts: an energy absorption module, an energy recovery module, and an energy conversion module. The energy absorption module includes four blades with staggered distribution in two layers. The overlap ratio of the blades can be adjusted by the wind speed, which can ensure the SVAWT has a higher energy transfer efficiency. The energy recovery module adjusts the overlap ratio of the blades without interruption by utilizing the self-rotation and the orbital revolution of the gears. The energy conversion module converts mechanical energy into electric energy and supplies power for the vehicle after adjustment by the voltage regulator module. Based on actual operating data, it can be found that the variation trend of power of the blades absorbing is consistent with wind speed and increases with the wind speed. Under four actual operating conditions, the root mean square value of the blades absorbing power are 7.0 W, 7.1 W, 3.9 W, and 5.1 W, respectively. These results reveal that the proposed novel adjustable SVAWT has high recovery power potential and can provide a valuable solution to the practical applications of wind energy harvesting.

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In the title compound, C10H13NO, the N atom and the methyl group are almost coplanar with the benzene ring to which they are bonded [deviations of 0.131 (1) and 0.038 (1) Å, respectively, from the ring plane]. In the crystal structure, inter­molecular C—H⋯O hydrogen bonds form a three-dimensional network. Mol­ecules are stacked parallel to the b-axis direction.