A method for electrochemical oxidative direct C(sp3)–H azolation under metal catalyst-free and external chemical oxidant-free conditions.

The synthesis of diarylamine is extremely important in organic chemistry. Herein, a novel electrochemical reductive arylation of nitroarenes with arylboronic acids was developed. A variety of diarylamines were synthesized without the need for transition‐metal catalysts. The reaction could be scaled up efficiently in a flow cell and several derivatization reactions were carried out smoothly. Cyclic voltammetry experiments and mechanism studies showed that acetonitrile, formic acid, and triethyl phosphite all played a role in promoting this reductive arylation transformation.

A general and effective protocol to synthesize α,α‐dibromo aryl ketones has been developed via an electrochemical oxidative method. The reaction proceeds smoothly at room temperature in an undivided cell without the addition of external oxidants. In the reaction process, LiBr acts as both bromine source and supporting electrolyte. This electrooxidation strategy has good substrate applicability and functional group compatibility. Moreover, the reaction could be scaled up efficiently in a continuous flow cell. The target product could undergo further functionalization for the synthesis of some useful heterocyclic compounds.

Uniaxial compression tests were carried out based on acoustic emission technology to study the rule and process of the damage evolution of marble powder concrete (MPC) under compression. The fracture characteristics of MPC are examined by analyzing the variation characteristics of acoustic emission signal parameters. The damage evolution model of MPC is established based on the characteristic parameters. The results showed that the strength loss rate of MPC decreased with the curing time, and the maximum strength loss rate of 28 d was 6.2% when the substitution percentage was 15%. According to the analysis of acoustic emission parameters, the compression failure process of MPC can be divided into three stages, the acoustic emission activity is higher in the early stage of loading, the relative stress during critical instability failure is reduced, and the substitution percentage is reduced by 4.2% at 15%. MPC is mainly fractured by tensile failure. With the increase in marble powder substitution percentage, the proportion of tensile mode cracks in stages I and II decreased. The proportion in stage III showed an increasing trend, and the failure characteristics gradually changed from brittleness to ductility. The fluctuation amplitude of the b-value increased with the substitution percentage, and the highest volatility was 18.5% when the substitution percentage was 15%. The crack propagation behavior gradually changed from stable growth to unstable growth. When the substitution percentage is lower than 15%, the damage development of MPC in the middle of stress (relative stress 20~70%) is relatively slow, and the damage development is accelerated in the late stress stage.