Homochiral crystallizations of two enantiomeric metal-organic frameworks (MOFs) Ce-MDIP1 and Ce-MDIP2 were achieved by using L- or D-BCIP as chiral inductions, respectively, where the chiralities were characterized by solid state CD spectra. Ce-MDIPs exhibit excellent catalytic activity and high enantioselectivity for the asymmetric cyanosilylation of aromatic aldehydes; the homochiral Cd-TBT MOF having L-PYI as a chiral adduct exhibits stereochemical catalysis toward the Aldol reactions.

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Through deposition of APTES-functionalized Al2O3 particles onto a coarse macroporous support, a new strategy to reduce the pore size and simutaneously promote a high density of heterogeneous nucleation sites was developed, and a continuous and thin ZIF-8 membrane exhibiting remarkably high H2 permeance of 5.73 × 10(-5) mol m(-2) s(-1) Pa(-1) and H2/N2 ideal selectivity of 15.4 was achieved.