A one-pot synthesis of dihydrobenzosiloles from styrenes has been developed. The reaction involves the nickel-catalyzed hydrosilylation of styrene with diphenylsilane, followed by the irridium-catalyzed dehydrogenative cyclization. This method is efficient for both electron rich and electron deficient styrenes, and exhibits good functional group tolerance, as well as excellent regioselectivity. The forming dihydrobenzosiloles can be efficiently converted into valuable benzosiloles or 2-hydroxyphenethyl alcohols.

We demonstrate an efficient conversion of highly-multimode (M2∼34) pump beam from fiber-combined 938-nm laser diodes into a 976-nm Stokes beam of high quality (M2=1.7-2 at output powers 10-52 W) that results in record brightness enhancement (BE=73) for Raman lasers based on graded-index fiber (GIF) and other fibers. The measured shapes of the output beams in GIF show that the near-parabolic pump beam becomes depleted above the Raman threshold so that the hole in the pump beam profile is much broader than the generated Stokes beam of near-Gaussian shape. The effect is analyzed in frames of a radially-dependent balance model with an account for the mode-selective feedback by FBG, which qualitatively describes the high-quality Stokes beam generation and the hole formation, but the hole width (and its power broadening) as well as the BE values are not consistent with experiment. Possible reasons for the difference are discussed.

Brönsted acid-catalyzed one-pot synthesis of indoles from o-aminobenzyl alcohols and furans has been developed. This method operates via the in situ formation of aminobenzylfuran, followed by its recyclization into the indole core. The method proved to be efficient for substrates possessing different functional groups, including -OMe, -CO2Cy, and -Br. The resulting indoles can easily be transformed into diverse scaffolds, including 2,3- and 1,2-fused indoles, and indole possessing an α,β-unsaturated ketone moiety at the C-2 position.

Various 2-substituted indolizines can be directly and selectively lithiated in the 5 position and subsequent reactions with different electrophiles lead to some novel classes of indolizines. In particular, previously unknown 5-formyl- and 5-iodoindolizine have been prepared by this way and the molecular structure of 5-formyl-2-phenylindolizine was confirmed by X-Ray analysis. The reactivity of the 5-CHO- and 5-COPh groups toward some nucleophiles has been examined, and some additional classes of derivatives (oximes and alcohols) have been obtained. The possibility of Suzuki cross-coupling of 5-iodoindolizines and boronic acids was proven.

Raman lasing in a graded-index fiber (GIF) attracts now great deal of attention due to the opportunity to convert high-power multimode laser diode radiation into the Stokes wave with beam quality improvement based on the Raman clean-up effect. Here we report on the cascaded Raman generation of the 2nd Stokes order in the 1.1-km long GIF with 100-μm core directly pumped by 915-nm diodes. In the studied all-fiber scheme, the 1st Stokes order is generated at 950–954 nm in a linear cavity formed at GIF ends by two fiber Bragg gratings (FBGs) securing beam quality improvement from M2 ≈ 30 to M2 ≈ 2.3 due to special transverse structure of FBGs. The 2nd Stokes wave is generated either in linear (two FBGs) or half-open (one FBG) cavity with random distributed feedback via Rayleigh backscattering. Their comparison shows that the random lasing provides better beam quality and higher slope efficiency. Nearly diffraction limited beam (M2 ≈ 1.6) with power up to 27 W at maximum gain (996 nm), and 17 W at the detuned wavelength of 978 nm has been obtained, thus demonstrating that the 2nd-order random lasing in diode-pumped GIF with FBGs provides high-efficiency high-quality beam generation in a broad wavelength range within the Raman gain spectral profile.