Методом активации на горячей поверхности (Hot Wire Chemical Vapor Deposition) осаждены тонкие фторполимерные пленки на наночастицы золота различного размера. С помощью многофункционального модульного прибора DSA-100 KRUSS определены значения краевых углов смачивания поверхности водой и CH2I2, также определена свободная энергия поверхности покрытий. Установлено влияние инкапсулированных частиц золота на гидрофобные свойства полученных покрытий. DOI: 10.21883/PJTF.2017.03.44226.16293

The synthesis of thin silver films by the gas-jet deposition method is experimentally and theoretically studied. When the metal is deposited onto silicon substrates from a supersonic jet of silver vapor with a helium carrier gas, nanostructured films with a 3−30 nm size of nanostructures are obtained for a 1230−1380 K range of jet source temperatures. The data on Ag–He gas-jet dynamics when it is expanded into vacuum (velocity, temperature, concentration, flux of particles onto a substrate) depending on parameters at the source (vapor temperature, flow rate of a carrier gas) are obtained by the method of direct simulation Monte Carlo. The range of optimal helium flow rates, when the efficiency of a gas-jet source is maximal, is determined. It is established that the presence of a background gas in a deposition chamber at pressure higher than 1 Pa decreases the flow of particles onto a substrate, and a simple way of its evaluation is proposed. Conditions for formation of silver clusters in the jet are determined by using the simulation. It is shown that for experimental deposition regimes there are no clusters in the jet, and the observed silver nanostructures are formed on the substrate surface.