A series of 3,3'-(4-arylpyridine-2,6-diyl)bis(2H-chromen-2-one) derviatives were synthesized by the one-pot three-component reaction of 3-acetyl coumarin, aromatic aldehydes, and ammonium acetate in acetic acid under microwave irradiation. The reactions were completed in 5~8 min with 60%~86% yields, and the procedure has the advantages of short reaction time, easy work-up and environmental begin. Their structures were confirmed by 1 H NMR, IR, MS techniques and elemental analysis.
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