The pheromone (R)‐(–)‐sulcatol (10a) and three of its enantiomeric mono‐, di‐, and trifluoro analogues 10b–d have been synthesized, in six steps and with good overall yields, starting from chiral (R)‐2‐methyl‐5‐[(4‐methylphenyl)sulfinyl]pent‐2‐ene (1) and commercially available fluorinated or non‐fluorinated acetates.