16. High performance liquid chromatography — Isotope dilution - inductively coupled plasma — mass spectrometry for lead and tin speciation in environmental samples

Hill, Steve J.; Brown, Alistair A.; Rivas, Cristina Soler; Sparkes, Simon T.; Ebdon, Les

doi:10.1016/s0167-9244(06)80017-x

Cited by 8 publications

(8 citation statements)

References 13 publications

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“…To determine the quality of water samples, Cl and salinity by Mohr-Knudsen method, Ca, Mg, total hardness by EDTA method, CO 3 , HCO 3 , total alkalinity by HCI titration method were analyzed with titrimetric analysis solutions (Greenberg et al, 1992 (HACH, 2010). The water was transferred to the ICP-OES spectrometer for As and Cd analysis; ICP-MS spectrometer for B analysis; AAS spectrometer for Na analysis (Morales-Rubio and De la Guardia, 1999;Hill et al, 1995;Kmiecik et al, 2016;Thompson and Wood, 1982). Fecal coliform were determined using a membrane filter set (TSE, 2014;Tekbaş and Oğur, 2005;Sartonet, 2015).…”

Section: Introductionmentioning

confidence: 99%

Chemical and microbiological properties of Lake Aygır in Turkey and usage of drinking, fisheries, and irrigation

Çavuş

Şen

2023

Braz. J. Biol.

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Since water is one of the essentials for life, the presence and quality of water in the habitat is extremely important. Therefore, water quality change and management of Lake Aygır was investigated in this study. For this, water samples collected from the lake and the irrigation pool between May 2015 and May 2016 were analyzed monthly. Spectrophotometric, titrimetric and microbiological methods were used to determine the water quality. According to some water quality regulations, HCO3, NH4, Cu, Mo, Br, fecal coliform and total suspended solid (TSS) values were found above the limit values. The other 29 parameters comply with Turkish national and international legislations. Lake Aygır was negatively affected by the surrounding settlements and agricultural activities. It is thought that the water resource should be monitored periodically and remedial studies should be done to prevent parameters exceeding the limits. However, Lake Aygır was generally suitable for drinking, use, fishing and irrigation.

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Section: Introductionmentioning

confidence: 99%

Chemical and microbiological properties of Lake Aygır in Turkey and usage of drinking, fisheries, and irrigation

Çavuş

Şen

2023

Braz. J. Biol.

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“…Despite development of sensitive and selective detection/quantitation techniques, primarily based on various chromatographies in combination with element-selective detection [5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21], there exists a need for Certified Reference Materials (CRMs) to provide traceability of data and quality control for validation. Species-specific CRMs are currently available from only a few reference material producers and the suite of analytes is quite limited, including Sn, Hg, As, Cr and Se [22].…”

Section: Introductionmentioning

confidence: 99%

Effects of γ-sterilization on butyltin homogeneity and content in sediments: a GC–ICP–MS study

et al. 2003

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A GC-ICP-MS method based on extraction and alkylation of butyltins with sodium tetraethylborate was used to quantitatively assess the fate of these analytes in solutions and sediments following exposure to gamma-irradiation. The effects of a 2.5 Mrad sterilization dose on three butyltin species in both methanolic calibration solutions and in sediment matrices were investigated. Although significant losses of tributyltin (TBT, 90%), dibutyltin (DBT, 100%) and monobutyltin (MBT, 80%) were detected in standard solutions prepared in methanol following gamma-irradiation, no species inter-conversion occurred. Some degradation of TBT (38%) and DBT (32%) but no significant change in MBT content was found using a spiked sediment CRM HISS-1. Conversion DBT to MBT in spiked HISS-1 was deduced. Much smaller degradation of TBT (16% loss) and 10% loss of DBT by conversion to MBT (14% gain) was registered using a sediment blend of PACS-2 and HISS-1 (SOPH). Despite some initial losses of TBT and DBT due to irradiation, better than 2% RSD in both TBT and DBT concentrations measured in twelve different bottles of blended sediment SOPH were obtained, indicating the material may be considered homogeneous for these analytes. Results from a long-term five-year stability study of PACS-2 show that all three butyltins are stable during storage at 4 degrees C followed with 2.5 Mrad minimum dose of gamma-irradiation sterilization treatment.

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“…35 If these are available, a number of advantages accrue with ID, including: enhanced precision and accuracy of results as the species specific spike serves as an ideal internal standard; matrix effects are accounted for since quantitation is done by ratio measurements; nonquantitative analyte recovery does not impact on the final results; and species alteration during sample work-up can be assessed. Only recently has this approach been applied to the determination of butyltin [24][25][26]31,32,36 and other species, including organolead, [31][32]37 methylmercury, [38][39] Cr (III and VI), 35 iodide, 40 methylselenocysteine, 41 and selenite 40,42 using synthesized species specific spikes.…”

Section: Introductionmentioning

confidence: 99%

“…[12][13][14][15][16][17][18][19][20][21] Over the past decade, inductively coupled plasma mass spectrometry (ICP-MS) has often been used as a sensitive and selective detector for butyltin determination when coupled to GC 12,20,[22][23][24][25][26][27][28] and HPLC. [29][30][31][32] It is well-known that ICP-MS possesses high sensitivity, a large dynamic range and multielement capability. Moreover, if two interference free isotopes of a given element are found, the isotope dilution (ID) calibration strategy can be applied, which generally provides superior accuracy and precision over other calibration strategies, including external calibration and standard additions.…”

Section: Introductionmentioning

confidence: 99%

Improvement in measurement precision with SPME by use of isotope dilution mass spectrometry and its application to the determination of tributyltin in sediment using SPME GC-ICP-MS

Yang

Mester

Sturgeon

2002

J. Anal. At. Spectrom.

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Access and use of this website and the material on it are subject to the Terms and Conditions set forth at Improvement in measurement precision with SPME by use of isotope dilution mass spectrometry and its application to the determination of tributyltin in sediment using SPME GC-ICP-MS Yang, L.; Mester, Z.; Sturgeon, R.http://nparc.cisti-icist.nrc-cnrc.gc.ca/npsi/jsp/nparc_cp.jsp?lang=fr L'accès à ce site Web et l'utilisation de son contenu sont assujettis aux conditions présentées dans le site LISEZ CES CONDITIONS ATTENTIVEMENT AVANT D'UTILISER CE SITE WEB. NRC Publications Record / Notice d'Archives des publications de CNRC:http://nparc.cisti-icist.nrc-cnrc.gc.ca/npsi/ctrl?action=rtdoc&an=8897925&lang=en http://nparc.cisti-icist.nrc-cnrc.gc.ca/npsi/ctrl?action=rtdoc&an=8897925&lang=fr READ THESE TERMS AND CONDITIONS CAREFULLY BEFORE USING THIS WEBSITE.http://nparc.cisti-icist.nrc-cnrc.gc.ca/npsi/jsp/nparc_cp.jsp?lang=en Vous avez des questions? Nous pouvons vous aider. Pour communiquer directement avec un auteur, consultez la première page de la revue dans laquelle son article a été publié afin de trouver ses coordonnées. Si vous n'arrivez pas à les repérer, communiquez avec nous à PublicationsArchive-ArchivesPublications@nrc-cnrc.gc.ca. Questions? Contact the NRC Publications Archive team atPublicationsArchive-ArchivesPublications@nrc-cnrc.gc.ca. If you wish to email the authors directly, please see the first page of the publication for their contact information. NRC Publications Archive Archives des publications du CNRCThis publication could be one of several versions: author's original, accepted manuscript or the publisher's version. / La version de cette publication peut être l'une des suivantes : la version prépublication de l'auteur, la version acceptée du manuscrit ou la version de l'éditeur. For the publisher's version, please access the DOI link below./ Pour consulter la version de l'éditeur, utilisez le lien DOI ci-dessous.http://doi.org/10.1039/b204157jJournal of Analytical Atomic Spectrometry, 17, 8, pp. 944-949, 2002 Improvement in measurement precision with SPME by use of isotope dilution mass spectrometry and its application to the determination of tributyltin in sediment using SPME GC-ICP-MS A method is described for the accurate and precise determination of tributyltin (TBT) by species specific isotope dilution mass spectrometry (ID-MS) using solid phase microextraction (SPME) in combination with gas chromatographic (GC) separation and inductively coupled plasma mass spectrometric (ICP-MS) detection. Butyltin compounds were ethylated in aqueous solution with sodium tetraethylborate and the headspace sampled with a polydimethylsiloxane coated fused silica SPME fiber. The analyte was then directly transferred from the fiber to the head of the GC column for desorption following insertion of the fiber through the heated injection port. Reverse spike ID analysis was performed to determine the accurate concentration of a 117 Snenriched TBT spike using two well characterized natural abundance TBT...

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16. High performance liquid chromatography — Isotope dilution - inductively coupled plasma — mass spectrometry for lead and tin speciation in environmental samples

Cited by 8 publications

References 13 publications

Chemical and microbiological properties of Lake Aygır in Turkey and usage of drinking, fisheries, and irrigation

Chemical and microbiological properties of Lake Aygır in Turkey and usage of drinking, fisheries, and irrigation

Effects of γ-sterilization on butyltin homogeneity and content in sediments: a GC–ICP–MS study

Improvement in measurement precision with SPME by use of isotope dilution mass spectrometry and its application to the determination of tributyltin in sediment using SPME GC-ICP-MS

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