1D, 2D and 3D coordination polymers of 1,3-phenylene diisonicotinate with Cu(i)/Cu(ii): Cu₂I₂ building block, anion influence and guest inclusions

Abstract

The reactions of a flexible bidentate ligand 1,3-phenylene diisonicotinate (L) with Cu(i/ii) salts afforded coordination polymers with varied dimensionalities and guest inclusion capabilities.

Synthesis, Characterization, and Optical Properties of Organic–Inorganic Hybrid Layered Materials: A Solvent-Free Ligand-Controlled Dimensionality Approach Based on Metal Sulfates and Aromatic Diamines

“…Nevertheless, a “single set of factors” that determines the dimensionality of the resulting framework of a hybrid organic–inorganic material has not been identified. Although many different organic molecule types have been used as templates − it is well-known that amines and diamines are very important building blocks in the synthesis of hybrid materials. − Paul et al and Liu et al present good examples of aromatic amines (specifically, polyazaheterocycles and triazole derivates) used as organic block and cadmium sulfates as inorganic part, where two-dimensional (2D) and 3D frameworks were synthesized. The use of different structural isomers as organic building blocks was previously studied by Thirumurugan and Rao and Zheng He et al Thirumurugan and Rao presented a group of hybrid compounds that contain isomers of benzenedicarboxylic acid as organic components in the presence or absence of amines, acting as chelating ligands, and Zn or Cd as metal centers.…”

Antitumor Properties of a New Macrocyclic Tetranuclear Oxidovanadium(V) Complex with 3-Methoxysalicylidenvaline Ligand

“…The frequency assignments were done based on our previous results [ 6 ] and those of other groups [ 16 , 30 ]. The compound is characterized by the appearance of low-intensity absorption bands up to 3000 cm −1 that can be attributed to aromatic and methoxy anion C-H stretch vibration [ 31 , 32 ].…”

Facile access to template-shape-replicated nitrogen-rich mesoporous carbon nanospheres for highly efficient CO2 capture and contaminant removal

“…); 1060 cm -1 (Si-O-Si linkage) 32 and 614 cm -1 (C-Br stretch.). 38 This indicates that integration of the bromo-initiator functionality into the pore walls of the silica framework was successful. The significant weight loss (16.4%) of MSN-Br between 120 and 800 °C was attributed to the organic (aminopropyl+2-bromoisobutyryl) functionalities, while the modest weight loss (8.4%) of neat MSN (Fig.…”