2-methylimidazole as a reagent for the photometric determination of maleic anhydride

Evtushenko, Yu. M.; Зайцев, Б. Е.; Иванов, В. М.; Gitis, K. M.

doi:10.1007/bf02757739

Cited by 1 publication

(2 citation statements)

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“…Each supercage is linked to six other supercages through prisms along the crystallographic axes. 37,38 The additional methylene group of 2-ethylimidazole (HeIm) enhances the linker basicity 39 and volatility, 40 making it highly suitable for vapor−solid reaction with ZnO.…”

Section: Introductionmentioning

confidence: 99%

“…The framework consists of truncated cuboctahedral supercages and octagonal prisms with the longest Zn–Zn distances of 2.80 and 1.69 nm, respectively. Each supercage is linked to six other supercages through prisms along the crystallographic axes. , The additional methylene group of 2-ethylimidazole (HeIm) enhances the linker basicity and volatility, making it highly suitable for vapor–solid reaction with ZnO.…”

Section: Introductionmentioning

confidence: 99%

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Solvent-Free Powder Synthesis and MOF-CVD Thin Films of the Large-Pore Metal–Organic Framework MAF-6

et al. 2020

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A simple solvent-and catalyst-free method is presented for the synthesis of the large-pore metal−organic framework (MOF) MAF-6 (RHO-Zn(eIm) 2) based on the reaction of ZnO with 2-ethylimidazole vapor at temperatures ≤100°C. By translating this method to a chemical vapor deposition (CVD) protocol, crystalline films of a large-pore material could be deposited for the first time entirely from the vapor phase. A combination of positron annihilation lifetime spectroscopy (PALS) and Kr physisorption measurements confirmed the porosity of these MOF-CVD films and the size of the MAF-6 supercages (diameter ∼2 nm), in close agreement with powder data and calculations. MAF-6 powders and films were further characterized by X-ray diffraction (XRD), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR), pair distribution function (PDF), and extended X-ray absorption fine structure (EXAFS). The exceptional uptake capacity of MAF-6 in comparison to ZIF-8 is demonstrated by vapor-phase loading of a molecule larger than the ZIF-8 windows. spectra; PALS data and implantation profiles; EDS data; fluorescence emission spectra (PDF)

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Section: Introductionmentioning

confidence: 99%