A Cationic, Macrocyclic, Six-Coordinate Phosphorus(V) Compound Containing a Mixed Valence PIII-PV-PIII Linear Chain

Luo, Hao; McDonald, Robert; Cavell, Ronald G.

doi:10.1002/(sici)1521-3773(19980504)37:8<1098::aid-anie1098>3.0.co;2-h

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Cited by 14 publications

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Use of Molecular Scaffolding for the Stabilization of an Intramolecular Dative P^III‐P^V System

et al. 2002

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The reaction of NapP 2 S 4 (1; Nap = naphthalene-1,8-diyl) with chlorine gas gave [Nap(PCl 2 )(PCl 4 )] (2), displaying a rare σ 4 P-σ 6 P bonding interaction. An X-ray structure analysis confirmed the PCl 5 -like, P−P bond containing phosphoniumphosphoride structure of 2 in the crystal, which was also found in solution at low temperature. At ambient and higher temperatures, dynamic behaviour on the NMR time-scale was observed, which was assigned to interchange of the ionic phosphonium-phosphoride form 2 and the molecular bis(phosphorane) Nap(PCl 3 ) 2 form 3, rather than to the ionic phosphonium salt-phosphorane form [Nap(PCl 3 )(PCl 2 )][Cl] 4. Electronic structure calculations were performed at the

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Use of Molecular Scaffolding for the Stabilization of an Intramolecular Dative P^III‐P^V System

et al. 2002

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Compounds with Phosphorus at the Spiro Position

Tebby

2001

Phosphorus-Carbon Heterocyclic Chemistry

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Compounds containing a Spiro Phosphorus Atom

Williams¹

2008

Comprehensive Heterocyclic Chemistry III

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A Cationic, Macrocyclic, Six-Coordinate Phosphorus(V) Compound Containing a Mixed Valence PIII-PV-PIII Linear Chain

Abstract: In the highly symmetrical environment of the P center in the cation [P{P(o-C H O) Ph} ] of 1 the two P -P bonds are relatively short (2.2023(10) Å) for compounds of this type. Compound 1 was obtained from the reaction of PCl with two equivalents of [(o-OSiMe )C H ] PPh.

Cited by 14 publications

References 15 publications

Use of Molecular Scaffolding for the Stabilization of an Intramolecular Dative P^III‐P^V System

Use of Molecular Scaffolding for the Stabilization of an Intramolecular Dative P^III‐P^V System

Compounds with Phosphorus at the Spiro Position

Compounds containing a Spiro Phosphorus Atom

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A Cationic, Macrocyclic, Six-Coordinate Phosphorus(V) Compound Containing a Mixed Valence PIII-PV-PIII Linear Chain

Abstract: In the highly symmetrical environment of the P center in the cation [P{P(o-C H O) Ph} ] of 1 the two P -P bonds are relatively short (2.2023(10) Å) for compounds of this type. Compound 1 was obtained from the reaction of PCl with two equivalents of [(o-OSiMe )C H ] PPh.

Cited by 14 publications

References 15 publications

Use of Molecular Scaffolding for the Stabilization of an Intramolecular Dative PIII‐PV System

Use of Molecular Scaffolding for the Stabilization of an Intramolecular Dative PIII‐PV System

Compounds with Phosphorus at the Spiro Position

Compounds containing a Spiro Phosphorus Atom

Contact Info

Product

Resources

About

Use of Molecular Scaffolding for the Stabilization of an Intramolecular Dative P^III‐P^V System

Use of Molecular Scaffolding for the Stabilization of an Intramolecular Dative P^III‐P^V System