A cellulose monolith supported metal/organic framework as a hierarchical porous material for a flow reaction

Abstract

A novel cellulose monolith supported ZIF-8 metal organic framework as a hierarchical porous material was designed by using a highly effective pump injection method, which is used for a flow-based reaction.

Metal–Organic Framework (MOF) Derived Recyclable, Superhydrophobic Composite of Cotton Fabrics for the Facile Removal of Oil Spills

“…Based on this advantage, a large number of cellulose-based superhydrophobic materials have been developed . Recently, such surface modification of cellulose material (cotton fabric) gas been achieved by highly porous MOF materials for various uses. − But, the surface modification of cellulose fiber with superhydrophobic MOF material for oil–water separation application has been rarely explored.…”

Uniform Growth of Nanocrystalline ZIF‐8 on Cellulose Nanocrystals: Useful Template for Microporous Organic Polymers

“…Recently, cellulose derivatives have also been used as a template. For example, when ZIF‐8 was introduced into films of cellulose fibers, cellulose monoliths, and CNC hydrogels, the resulting materials showed good capability in air filtration, [17] catalysis, [18] and filament formation, [9] respectively. However, the ZIF‐8 crystals were heterogeneously and randomly synthesized owing to the difficulty of controlling nucleation only on the material surface [9, 17, 18] .…”

“…However, the ZIF-8 crystals were heterogeneously and randomly synthesized owing to the difficulty of controlling nucleation only on the material surface. [9,17,18] Moreover, only film and hydrogel forms of ZIF-8 functionalized cellulose derivatives have been reported; [19][20][21][22][23][24][25] MOPs have not yet been combined with CNCs to produce composite materials.…”

Tubular Catalytic Polyhipe Reactor with Deposited Silver Nanoplate Nanoparticles

“…The combination of catalyst nanoparticles with an inert porous matrix seems to be the method of choice to prepare highly permeable catalytic reactors while minimizing the amount of required catalyst. There are several approaches to construct such catalytic reactors, either by in situ catalyst synthesis [5][6][7][8][9][10][11][12] or by depositing already pre-synthesized NP and stabilizing them by various interactions [13][14][15].…”