A centric thiuram disulfide. Structure of tetraisopropylthiuram disulfide

Bis(N,N-dicyclohexylthiocarbamoyl) disulfide

“…The disulfide S-S distance is close to the distances observed in free (uncoordinated) disfulfides (Kumar et al, 1990). The Csp 2 -N bond distance observed in this complex is similar to that observed in analogous compounds, confirming the considerable double-bond character associated with these bonds.…”

Bis(N,N-dibenzylthiocarbamoyl) disulfide

“…In (I) ( Fig. 1), the S-S bond length of 1.9910 (13) Å is slightly shorter than that observed in bis(N,N-dicyclohexylthiocarbamoyl) disulfide (Li et al, 2006) and in free (uncoordinated) disulfides (Kumar et al, 1990). The torsion angle C1-S1-S3-C16 is À85.71 (13) .…”

Crystal structure of tetraisobutylthiuram disulfide

“…Values for and for structures in the Cambridge Structural Database (Web CSD v1.1.1; Groom et al, 2016) were determined using Mercury (Macrae et al, 2008). These structures are: METHUS (Marøy, 1965), METHUS01 (Ymé n, 1983), METHUS02 (Wang et al, 1986), METHUS03 (Wang & Liao, 1989), METHUS04 (Wang & Liao, 1989), ETHUSS (Karle et al, 1967) ETHUSS01 (Wang et al, 1986), ETHUSS02 (Wang & Liao, 1989), ETHUSS03 (Wang & Liao, 1989), ETHUSS04 (Shi & Wang, 1992), ETHUSS05 (Hu, 2000), HIQJUM (Jian et al, 1999), HIQJUM01 (Yu & Wang, 2003), JECYAZ (Kumar et al, 1990), TIBFEQ (Zhai et al, 2007), ZEMPUC (Hall & Tiekink, 1995), KAZHEA (Karim et al, 2012), NELTUT (Fun et al, 2001), XEBJOF (Ajibade et al, 2012), JAXPOO (Raya et al, 2005), CAPLEK (Williams et al, 1983), CAPLEK01 (Ymé n, 1983), CAPLEK02 (Yamin et al, 1996), CAPLEK03 (Bai et al, 2010), RISNEN (Quan et al, 2008), ULOXIC (Bodige & Watson, 2003), PIPTHS (Dix & Rae, 1973), PIPTHS01 (Shi & Wang, 1992), EWESUW (Nath et al, 2016), BOMPAU (Rout et al, 1982), VOHFIH (Polyakova & Starikova, 1990), VOHFIH01 (Ivanov et al, 2003), PECWOL…”