A comparative investigation: Evaluating the epoxidation of styrene with binuclear molybdenum(VI) complexes under conventional heating and microwave-assisted conditions

Rana, Lata; Mahendrabhai, Rughani Kashyap; Dheeraj,; Desai, Meghal A.; Hundal, Geeta

doi:10.1016/j.molstruc.2023.137103

Journal of Molecular Structure

2024

DOI: 10.1016/j.molstruc.2023.137103

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A comparative investigation: Evaluating the epoxidation of styrene with binuclear molybdenum(VI) complexes under conventional heating and microwave-assisted conditions

Lata Rana,

Rughani Kashyap Mahendrabhai,

Dheeraj

et al.

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Cited by 2 publications

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Selective Oxidative Scission of Olefins to Aldehydes Enabled by Ruthenium Complexes Containing Salicylaldimine Ligands

Xu,

Xing,

Hao

et al. 2024

Applied Organom Chemis

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Treatment of Ru3(CO)12 with salicylaldimine ligands [ArNCH(3‐tBuC6H3OH) [ArC6H5 (L1H); 4‐OMeC6H4 (L2H); 4‐MeC6H4 (L3H); 2,4,6‐Me3C6H2 (L4H); 4‐ClC6H4 (L5H); 4‐BrC6H4 (L6H)] in refluxing toluene afforded six bis‐ligand mononuclear ruthenium carbonyl complexes [ArNCH(3‐tBuC6H3O)]2Ru(CO)2 1a–1f in good yields. All of the Ru(II) complexes were characterized using IR, NMR, and elemental analysis. The molecular structures of complexes 1a, 1b, 1e, and 1f were further confirmed through X‐ray diffraction analysis. Additionally, the catalytic performance of these complexes was investigated in the oxidation of olefins to aldehydes, using TBHP as the oxidant in refluxing trichloromethane. With 1.0 mol% catalyst loading, these ruthenium complexes displayed high reactivity and good functional‐group compatibility, selectivity providing the corresponding oxidation product aldehydes in 73%–94% yields.

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Selective Oxidative Scission of Olefins to Aldehydes Enabled by Ruthenium Complexes Containing Salicylaldimine Ligands

Xu,

Xing,

Hao

et al. 2024

Applied Organom Chemis

View full text Add to dashboard Cite

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Surface-decorated magnetite nanoparticles with dioxidomolybdenum(VI) complexes as a catalyst for alkene epoxidation

Rana,

Dheeraj,

Desai

2025

Journal of Molecular Structure

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A comparative investigation: Evaluating the epoxidation of styrene with binuclear molybdenum(VI) complexes under conventional heating and microwave-assisted conditions

Cited by 2 publications

References 36 publications

Selective Oxidative Scission of Olefins to Aldehydes Enabled by Ruthenium Complexes Containing Salicylaldimine Ligands

Selective Oxidative Scission of Olefins to Aldehydes Enabled by Ruthenium Complexes Containing Salicylaldimine Ligands

Surface-decorated magnetite nanoparticles with dioxidomolybdenum(VI) complexes as a catalyst for alkene epoxidation

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