A comparative study of palladium-based coordination compounds with bidentate (N,N, P,P and P,O) ligands; Design, synthesis, X-ray structural, catalytic activity and DFT studies

Naghipour, Ali; Sayadi, Mohsen; Sedghi, Asieh; Sabounchei, Seyyed Javad; Babaee, Heshmatollah; Notash, Behrouz

doi:10.1016/j.ica.2020.120039

Cited by 7 publications

(1 citation statement)

References 53 publications

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“…Palladium complexes containing 1,2-bis(diphenylphosphanyl)ethane as a ligand have received much attention over the last decade because of their application in catalysis (Naghipour et al, 2021;Thapa et al, 2019). Recently, some of the focus has shifted to exploring their cytotoxicity (Cullinane et al, 2018;Kuijpers & Blom, 2021) and biological activity (Al-Janabi et al, 2021).…”

Section: Structure Descriptionmentioning

confidence: 99%

[1,2-Bis(diphenylphosphanyl)ethane-κ² P,P]chlorido(isonicotinamide-κN)palladium(II) nitrate acetonitrile monosolvate

2021

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The PdII central atom in the title complex, [PdCl(C26H24P2)(C6H6N2O)]NO3·CH3CN or [PdCl(dppe)(INAM)]NO3·CH3CN, where dppe is 1,2-bis(diphenylphosphanyl)ethane and INAM is isonicotinamide, exists in a slightly distorted square-planar environment defined by the two P atoms of the dppe ligand, a chloride ligand and the N atom of the isonicotinamide pyridyl ring. The crystal packing in the structure is held together by hydrogen bonds between the amide of the INAM ligand and the nitrate ions that complete the outer coordination sphere. A molecule of acetonitrile is also found in the asymmetric unit of the title complex.

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Section: Structure Descriptionmentioning

confidence: 99%

[1,2-Bis(diphenylphosphanyl)ethane-κ² P,P]chlorido(isonicotinamide-κN)palladium(II) nitrate acetonitrile monosolvate

2021

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Influence of the structure of benzylaminate C,N-palladacycles on their catalytic activity in the Suzuki—Miyaura reaction

Gorunova,

Timerkaeva,

Kochetkov

et al. 2024

Russ Chem Bull

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Effect of highly active oxygen on methane catalytic removal at low temperatures using a core–shell structural catalyst

Geng

Zhao

Huang

et al. 2023

Chemical Engineering Journal

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A comparative study of palladium-based coordination compounds with bidentate (N,N, P,P and P,O) ligands; Design, synthesis, X-ray structural, catalytic activity and DFT studies

Cited by 7 publications

References 53 publications

[1,2-Bis(diphenylphosphanyl)ethane-κ² P,P]chlorido(isonicotinamide-κN)palladium(II) nitrate acetonitrile monosolvate

[1,2-Bis(diphenylphosphanyl)ethane-κ² P,P]chlorido(isonicotinamide-κN)palladium(II) nitrate acetonitrile monosolvate

Influence of the structure of benzylaminate C,N-palladacycles on their catalytic activity in the Suzuki—Miyaura reaction

Effect of highly active oxygen on methane catalytic removal at low temperatures using a core–shell structural catalyst

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A comparative study of palladium-based coordination compounds with bidentate (N,N, P,P and P,O) ligands; Design, synthesis, X-ray structural, catalytic activity and DFT studies

Cited by 7 publications

References 53 publications

[1,2-Bis(diphenylphosphanyl)ethane-κ2 P,P]chlorido(isonicotinamide-κN)palladium(II) nitrate acetonitrile monosolvate

[1,2-Bis(diphenylphosphanyl)ethane-κ2 P,P]chlorido(isonicotinamide-κN)palladium(II) nitrate acetonitrile monosolvate

Influence of the structure of benzylaminate C,N-palladacycles on their catalytic activity in the Suzuki—Miyaura reaction

Effect of highly active oxygen on methane catalytic removal at low temperatures using a core–shell structural catalyst

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[1,2-Bis(diphenylphosphanyl)ethane-κ² P,P]chlorido(isonicotinamide-κN)palladium(II) nitrate acetonitrile monosolvate

[1,2-Bis(diphenylphosphanyl)ethane-κ² P,P]chlorido(isonicotinamide-κN)palladium(II) nitrate acetonitrile monosolvate