Abstract:Hydrogels are excellent soft materials to interface with biological systems. Precise control and tunability of dissipative properties of gels are particularly interesting in tissue engineering applications. In this work, we...
“…Hydrogels are fabricated first via different crosslinking methods and subsequently immersed in the TA solution for secondary crosslinking, which can provide hydrogels with high mechanical properties and multifunctionality such as adhesiveness and self-healing properties as well as superior biological activities compared to the untreated hydrogel. [236][237][238] A wide range of hydrogels comprising natural and synthetic polymers have been exposed to the TA solution to form hydrogel through a simple, feasible, and expeditious method. However, in this system, a hydrogel should be prepared before the treatment with TA solution.…”
Section: Immersing Of Hydrogels In Ta Solutionmentioning
Engineering biomaterials for tissue healing and regeneration using natural compounds have gained much attention in recent years. As a hydrolysable tannin derivative of gallic acid with several water-soluble polar groups...
“…Hydrogels are fabricated first via different crosslinking methods and subsequently immersed in the TA solution for secondary crosslinking, which can provide hydrogels with high mechanical properties and multifunctionality such as adhesiveness and self-healing properties as well as superior biological activities compared to the untreated hydrogel. [236][237][238] A wide range of hydrogels comprising natural and synthetic polymers have been exposed to the TA solution to form hydrogel through a simple, feasible, and expeditious method. However, in this system, a hydrogel should be prepared before the treatment with TA solution.…”
Section: Immersing Of Hydrogels In Ta Solutionmentioning
Engineering biomaterials for tissue healing and regeneration using natural compounds have gained much attention in recent years. As a hydrolysable tannin derivative of gallic acid with several water-soluble polar groups...
“…Recently, the production of DN hydrogels through immersion in TA solution has drawn great scientific interest that can provide hydrogels with superior mechanical properties and versatile functions such as adhesiveness and self-healing properties as well as biological activities compared to untreated hydrogels (X. Li et al, 2020;Narasimhan et al, 2021;Wen et al, 2020).…”
“…The acrylamide group is known to be a hydrogen bond acceptor, while acrylic acid is a hydrogen bond donor. [67,68] Photopolymerization of AM and AA leads to the formation of the polymer phase stabilized by hydrogen bonding interactions between amide and carboxylic acid groups. Furthermore, AuNRs functionalized with double-stranded DNA (dsDNA) were introduced as multi-valent crosslinkers (Figure 1).…”
Section: Molecular Design and Componentsmentioning
Orientational control of anisotropic plasmonic nanoparticles is an attractive proposition to generate dynamic plasmonic responses. Particularly, the use of light as a stimulus to modulate the orientation is extremely useful owing to its spatiotemporal operative ability. This work showcases a light-mediated approach to tune the orientational features of gold nanorods in DNAengineered hydrogel materials. The strategy relies on the use of visible-lightinduced photothermal effects to cause deformation of the hydrogel matrix, resulting in temperature-controlled polarization-dependent optical responses whose anisotropy features are highly adaptive to the nature of DNA crosslinks. The visible-light-mediated approach showcased here can open novel avenues to create dynamic light-responsive materials with reconfigurable plasmonic responses.
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