2024
DOI: 10.1002/cptc.202400134
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A Compendium of Methodically Determined Ground‐ and Excited‐State Properties of Homoleptic Ruthenium(II) and Osmium(II) Photosensitizers

Felix Glaser,
Simon De Kreijger,
Katerina Achilleos
et al.

Abstract: The one‐pot synthesis of a total of 32 ruthenium(II) and osmium(II) photosensitizers bearing substituted 2,2’‐bipyridines, 1,10‐phenanthrolines, and diaza ligands is reported. Whereas most of these photosensitizers were already reported in the literature, the present study offers extensive datasets of ground‐ and excited‐state properties highly desirable for future development in e.g., machine learning, artificial intelligence, and photoredox catalysis. All photosensitizers absorbed light intensely in the visi… Show more

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