2023
DOI: 10.1002/admi.202300399
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A Complementary Experimental and Theoretical Approach for Probing the Surface Functionalization of ZnO with Molecular Catalyst Linkers

Abstract: The application of ZnO materials as solid‐state supports for molecular heterogeneous catalysis is contingent on the functionalization of the ZnO surface with stable self‐assembled monolayers (SAMs) of catalyst linker molecules. Herein, experimental and theoretical methods are used to study SAMs of azide‐terminated molecular catalyst linkers with two different anchor groups (silane and thiol) on poly and monocrystalline (0001, ) ZnO surfaces. Angle‐resolved and temperature‐dependent X‐ray photoelectron spectros… Show more

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