A Concise Stereoselective Total Synthesis of (–) - Cephalosporolide D

Yapuri, Umanadh; Omprakash, G.; Srinivasareddy, Narahari

doi:10.2174/157017861206150604154329

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H) Srinivasareddy's Synthesis Of (à)-Cephalosporolide D (2015)1

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“…Srinivasareddy and co-workers [32] also used (S)-propylene oxide 27 obtained from (AE)-propylene oxide by HKR and treated it with Grignard reagent prepared from 49 (Scheme 9). The resultant secondary alcohol on silyl protection gave 50.…”

Section: H) Srinivasareddy's Synthesis Of (à)-Cephalosporolide D (2015)mentioning

confidence: 99%

Total Synthesis of Marine Natural Products: Cephalosporolides

Halle

Fernandes

2016

Asian J Org Chem

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Marine-derived species, in particular, fungi, algae, sponges, and coelenterates are fertile grounds for the discovery of biologically and pharmacologically potent compounds. These molecules are structurally unique and possess a wide range of pharmacological activities. The rigid spiroacetal framework, that is, tetrahydro-spirofurofuranones is present in cephalosporolides E, F, H, and I, while the macrolactone structure is exemplified by cephalosporolides B, C, D, G, and J. These marine-derived molecular architectures are appealing to the synthetic community for their stereoselective synthesis. The present review represents a comprehensive overview of all the reported syntheses of these marine-derived molecules.

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Section: H) Srinivasareddy's Synthesis Of (à)-Cephalosporolide D (2015)mentioning

confidence: 99%