2024
DOI: 10.1002/ejic.202400578
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A Dehydrocoupling Approach Towards Titanocene Iminophosphane Complexes

Andrey Petrov,
Christian Hering‐Junghans

Abstract: Dehydrocoupling reactions represent a powerful tool for element‐element bonds formation upon H2 elimination. It was shown that transition metals (in low oxidation states or in the form of hydrides) can be coupled with two equivalents of primary pnictanes (R–PnH2; Pn = P, Sb) providing direct access to otherwise elusive η2‐dipnictene (R–Pn=Pn–R) complexes. Herein, we report on the reactivity of the common group IV metallocene precursors Cp2Ti(btmsa) and Cp2Zr(btmsa)(pyridine) (btmsa = C2(SiMe3)2) towards primar… Show more

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