A gel polymer electrolyte based on a novel synthesized matrix of a self-doped polymer of h-poly(methyl methacrylate-vinyl trismethoxy silane)

Huang, Yun; Huang, Rui; Shuili, Gong; Cao, Haijun; Lin, Yuanhua; Yang, Man; Xing, Li

doi:10.1039/c4ra16879h

Cited by 9 publications

(2 citation statements)

References 54 publications

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“…Furthermore, the cage structured POSS effectively increased the amorphous regions of host polymers and provided abundant free volume for Li‐ion migration. [ 179–183 ]…”

Section: Organosilicon For Li‐ion Batterymentioning

confidence: 99%

Organosilicon‐Based Functional Electrolytes for High‐Performance Lithium Batteries

Wang

Chen

et al. 2021

Advanced Energy Materials

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Nowadays excessive consumption of fossil fuels due to population growth and industrial development induced serious energy and environmental crisis. To alleviate the ecological crisis and comply with the ever-increasing energy demand, developingThe electrolyte has been considered as a key factor toward higher energy density for Li-ion and Li-metal batteries. However, conventional electrolytes suffer from uncontrolled interfacial reactions and irreversible decomposition causing performance deterioration and potential safety hazard. Organosilicon compounds have attracted great interest as promising electrolyte components due to facile chemical modifications, low glass transition temperatures (T g ), superior chemical, and thermal stabilities. Considerable investigation efforts have been devoted to developing better overall performance of organosilicon-based electrolytes in the past few years. Herein, the recent research progress of organosilicon-based functional electrolytes for the development of liquid, gel, and solid state electrolytes in Li-ion and Li-metal batteries is summarized. Attention is devoted to various types of organosilicon such as silane, siloxane, polysiloxane, and polyhedral oligomeric silsesquioxanes in terms of molecular design, ionic conductivity, functions shown in batteries, thermal, chemical, electrochemical stability, safety, etc. The feasible strategies are also discussed that may promote the comprehensive electrochemical performances of organosilicon-based electrolytes in different types of electrolytes and batteries. Finally, the challenges facing organosilicon-based electrolytes and proposed their possible solutions are presented alongside promising development directions.

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“…Furthermore, the cage structured POSS effectively increased the amorphous regions of host polymers and provided abundant free volume for Li‐ion migration. [ 179–183 ]…”

Section: Organosilicon For Li‐ion Batterymentioning

confidence: 99%

Organosilicon‐Based Functional Electrolytes for High‐Performance Lithium Batteries

Wang

Chen

et al. 2021

Advanced Energy Materials

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“…Its problem raises serious safety concerns. For this reason, gel polymer electrolytes (3) are being explored as a replacement for liquid electrolytes (4).…”

Section: Introductionmentioning

confidence: 99%

Electrochemical Properties of Gel Polymer Electrolytes with Flame Retardant Used as Solvent

Veselkova¹,

Jahn²,

Sedlařı́ková³

et al. 2018

ECS Trans.

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This paper deals with a method of preparation of gel polymer electrolytes modified by flame retardants. The method is characterized that as a solvent, one type of flame retardant is used here. Other components from basic chemical composition of a gel electrolyte didn’t change. The work is focused on measuring electrochemical and electrical properties of gel polymer electrolyte. Electrochemical properties were measured by linear voltammetry and impedance spectroscopy.

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Investigations of Relaxation Dynamics and Observation of Nearly Constant Loss Phenomena in PEO 20 -LiCF 3 SO 3 -ZrO 2 Based Polymer Nano-Composite Electrolyte

Dam

Tripathy

Paluch

et al. 2016

Electrochimica Acta

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A gel polymer electrolyte based on a novel synthesized matrix of a self-doped polymer of h-poly(methyl methacrylate-vinyl trismethoxy silane)

Abstract: The monomers of methyl methacrylate and vinyl trismethoxy silane were chosen to synthesize the novel self-doped polymer of (h-P(MMA-VTMS)), and then the obtained polymer was used as matrix to prepare GPE.

Cited by 9 publications

References 54 publications

Organosilicon‐Based Functional Electrolytes for High‐Performance Lithium Batteries

Organosilicon‐Based Functional Electrolytes for High‐Performance Lithium Batteries

Electrochemical Properties of Gel Polymer Electrolytes with Flame Retardant Used as Solvent

Investigations of Relaxation Dynamics and Observation of Nearly Constant Loss Phenomena in PEO 20 -LiCF 3 SO 3 -ZrO 2 Based Polymer Nano-Composite Electrolyte

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