A general spin Hamiltonian to describe ligand hyperfine structure. Its application to heme-proteins. I. Nuclear Zeeman and hyperfine interactions

Calvo, Rafael

doi:10.1016/0022-2364(77)90096-8

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Paramagnetic Inorganic Materials1

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1978

1984

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Cited by 3 publications

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“…Explicit derivations of the expressions necessary to analyze the ESR spectra of low-spin heme iron centers have been described (166). A method for deriving a spin-Hamiltonian which describes ligand hyperfine structure of isolated paramagnetic centers has been developed (167) and applied to ENDOR data for high-spin heme proteins. Planar low-spin CoN2S2 Schiff base chromophores have been investigated (168) and it was concluded that the unpaired electron resides in a cLz orbital on the metal.…”

Section: Paramagnetic Inorganic Materialsmentioning

confidence: 99%