A Gold Rush: Designing Hydrogels for Selective Recovery in Wastewater Containing Mixed Metal Ions

Abstract

The use of synthetic hydrogels in wastewater treatment represents a promising and scalable approach to achieving clean water. By modulation of their chemical structure, hydrogels can effectively remove a wide range of toxic compounds, including emerging organic pollutants and heavy metals. For the latter, recovery is essential for both environmental protection and metal recycling. The increasing demand for gold, a nonrenewable metal widely used in many technologies, calls for methods for its selective recovery from complex metal cation solutions. This study explores easy-to-make poly(acrylamide-co-acrylic acid) hydrogels as adsorbents for gold recovery from industrial wastewater containing other precious metals. Such material can reduce gold cations into elemental nanoparticles and microparticles in acid environments at room temperature. This process offers a potential route for metal recovery that is not based on weak interaction or complex formation. Batch tests demonstrate a good adsorption capacity (up to 124 mg/g) and efficient separation from other precious metal ions (Ru, Ir, Pd, Pt, and Rh) in a solution that closely mimics realistic industrial waste conditions. These hydrogels would enable gold recovery also from other complex metal solutions, including those derived from the dissolution of electronic wastes.