A hydrophobic phenolic polymer layer with high-flux Zn<sup>2+</sup>-specific regular channels for stabilizing aqueous zinc anodes

Shu, Tie; Yang, Xin; Huang, Zhou; Qiao, Min; Ning, Jiaoyi; Li, Kailin; Zhang, Yuxin; Li, Liang; Liu, Xin; Yao, Ke Xin

doi:10.1039/d3ta06472g

J. Mater. Chem. A

2024

DOI: 10.1039/d3ta06472g

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A hydrophobic phenolic polymer layer with high-flux Zn²⁺-specific regular channels for stabilizing aqueous zinc anodes

Tie Shu,

Xin Yang,

Zhou Huang

et al.

Abstract: Aqueous zinc-ion batteries (AZBs) hold great promise as a viable candidate for future large-scale energy storage systems. However, the persistent issues of dendrite growth and side reactions have been major...

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Cited by 6 publications

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In Situ Assembly of Metal‐Organic Coordination Polymer Layers Enables Highly Reversible Zn Anodes with a Long Cycle Life of over 6900 h

Shen,

Fang,

et al. 2024

Adv Funct Materials

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Zn anodes in aqueous zinc‐ion batteries chronically suffer from pernicious side reactions and ineluctable dendrite growth, resulting in inadequate reversibility and suboptimal Coulombic efficiency (CE) and impeding commercialization. Herein, a multifunctional metal–organic coordination polymer layer (FAZ) is constructed on the zinc anode surface (FAZ@Zn) utilizing a simple self‐assembly strategy. The zincophilic FAZ interfacial layer with a high Zn2+ transfer number and low nucleation barrier effectively facilitates the de‐solvation process, supports the rapid transport of zinc ions, and contributes to the preferential growth of Zn (002) crystal planes, enabling dendrite‐free Zn deposition. Furthermore, the FAZ layer, as an interfacial pH regulating layer, effectively inhibits the direct contact between Zn and active water molecules, lowering the severity of side reactions. Consequently, the FAZ@Zn anode furnishes an eminent cycle stability over 6900 h, with a low polarization voltage at 1 mA cm−2 and 1 mA h cm−2 and a boosted CE of 99.88% over 4100 cycles. More encouragingly, when coupled with Na2V6O16·3H2O, the FAZ@Zn anode enables the full cell to deliver satisfactory rate performance and a 97% capacity retention over 1600 cycles. This work provides a simple strategy for the effective preparation of highly reversible zinc anodes for high‐performance aqueous zinc‐ion batteries.

show abstract

In Situ Assembly of Metal‐Organic Coordination Polymer Layers Enables Highly Reversible Zn Anodes with a Long Cycle Life of over 6900 h

Shen,

Fang,

et al. 2024

Adv Funct Materials

View full text Add to dashboard Cite

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Hydrophobic conjugated microporous polymer with hierarchical porous structure for multifunctional modification of Zn metal anodes

Yi,

Wang,

Zhang

et al. 2025

Journal of Energy Storage

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Achieving dendrite-free growth of Zn anode by electrodepositing on zincophilic gold-furnished mesh for aqueous zinc-ion batteries

Liao,

Shu,

Yang

et al. 2024

Chem. Commun.

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A hydrophobic phenolic polymer layer with high-flux Zn²⁺-specific regular channels for stabilizing aqueous zinc anodes

Abstract: Aqueous zinc-ion batteries (AZBs) hold great promise as a viable candidate for future large-scale energy storage systems. However, the persistent issues of dendrite growth and side reactions have been major...

Cited by 6 publications

References 64 publications

In Situ Assembly of Metal‐Organic Coordination Polymer Layers Enables Highly Reversible Zn Anodes with a Long Cycle Life of over 6900 h

In Situ Assembly of Metal‐Organic Coordination Polymer Layers Enables Highly Reversible Zn Anodes with a Long Cycle Life of over 6900 h

Hydrophobic conjugated microporous polymer with hierarchical porous structure for multifunctional modification of Zn metal anodes

Achieving dendrite-free growth of Zn anode by electrodepositing on zincophilic gold-furnished mesh for aqueous zinc-ion batteries

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A hydrophobic phenolic polymer layer with high-flux Zn2+-specific regular channels for stabilizing aqueous zinc anodes

Abstract: Aqueous zinc-ion batteries (AZBs) hold great promise as a viable candidate for future large-scale energy storage systems. However, the persistent issues of dendrite growth and side reactions have been major...

Cited by 6 publications

References 64 publications

In Situ Assembly of Metal‐Organic Coordination Polymer Layers Enables Highly Reversible Zn Anodes with a Long Cycle Life of over 6900 h

In Situ Assembly of Metal‐Organic Coordination Polymer Layers Enables Highly Reversible Zn Anodes with a Long Cycle Life of over 6900 h

Hydrophobic conjugated microporous polymer with hierarchical porous structure for multifunctional modification of Zn metal anodes

Achieving dendrite-free growth of Zn anode by electrodepositing on zincophilic gold-furnished mesh for aqueous zinc-ion batteries

Contact Info

Product

Resources

About

A hydrophobic phenolic polymer layer with high-flux Zn²⁺-specific regular channels for stabilizing aqueous zinc anodes