“…LIBs comprise the cathode, anode, separator, current collector, electrolyte, and battery housing. [ 27 , 28 ] Their degradation can be minimized in smart electrodes via preventive steps, like artificial interfaces, [ 29 ] coatings, [ 30 , 31 , 32 , 33 , 34 , 35 ] self‐healing binders, [ 36 , 37 , 38 , 39 , 40 ] liquid metal alloys, [ 41 , 42 , 43 , 44 , 45 , 46 , 47 ] microcapsules, [ 48 , 49 , 50 ] and current collectors. [ 51 ] For instance, silicon (Si) anode severe volume expansion of up to 300% in the lithiation state leads to solid electrolyte interface (SEI) rupture, which decreases the electrochemical performance of LIB during cycling processes, and its lifetime become shortened.…”