A linear Cu (II) coordination polymer based on a simple click chelator

Fu, Yang; Li, Hua; Chen, Xingguo; Qin, Jingui

doi:10.1016/j.inoche.2010.11.011

Cited by 11 publications

(1 citation statement)

References 28 publications

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“…Although this fact is rare, it is not unique. In fact, among the several thousands of azido complexes, the CCDC data base shows seven other examples of azido-bridged complexes containing Cu ions with coordination numbers of 4, 5 and 6 [44][45][46][47][48].…”

Section: Description Of the Structure Of [Cumentioning

confidence: 99%

A rare polymeric azido-bridged copper(II) chain with a pentameric repeating unit: Synthesis, structure and magnetic properties

et al. 2013

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Section: Description Of the Structure Of [Cumentioning

confidence: 99%

A rare polymeric azido-bridged copper(II) chain with a pentameric repeating unit: Synthesis, structure and magnetic properties

et al. 2013

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Introducing Potential Hemilability into “Click” Triazoles and Triazolylidenes: Synthesis and Characterization of d⁶‐Metal Complexes and Oxidation Catalysis

2014

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Hemilabile ligands are known to impart remarkable properties to their metal complexes. Herein, we present arene half‐sandwich complexes of RuII, OsII, and IrIII with “click”‐derived 1,2,3‐triazole (L1) and 1,2,3‐triazol‐5‐ylidene (L2) ligands containing a potentially hemilabile thioether donor. Structural elucidation of the complexes revealed localization of double bonds within the triazole in L1 and a delocalized situation within the triazolylidene ring of L2. For complexes with L1, unusual coordination occurs through the less basic nitrogen “N2” of the 1,2,3‐triazole. All complexes were applied for the catalytic oxidation of benzyl alcohol to benzaldehyde using N‐methylmorpholine N‐oxide as sacrificial oxidant. Furthermore, oxidation of diphenylmethanol to benzophenone was also achieved by using low catalyst loadings in very good yields. These are rare examples of OsII–triazole, as well as of OsII–triazolylidene complexes with “click”‐derived ligands.

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Metal Complexes of Click-Derived Triazoles and Mesoionic Carbenes: Electron Transfer, Photochemistry, Magnetic Bistability, and Catalysis

Schweinfurth

Hettmanczyk

Suntrup

et al. 2017

Z. Anorg. Allg. Chem.

162

104

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Abstract. Even though the existence of 1,2,3-triazoles has been known for more than a century, the recent discovery of a copper(I) catalyzed version of this reaction has attributed unprecedented importance to these compounds. Coordination and organometallic chemists have benefited from this modular synthetic route, and have accessed ligands based on both the triazoles as well as the triazolylidenes. The wide variation of steric and electronic properties that can be achieved for this ligand class has made them useful for generating metal complexes

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A linear Cu (II) coordination polymer based on a simple click chelator

Cited by 11 publications

References 28 publications

A rare polymeric azido-bridged copper(II) chain with a pentameric repeating unit: Synthesis, structure and magnetic properties

A rare polymeric azido-bridged copper(II) chain with a pentameric repeating unit: Synthesis, structure and magnetic properties

Introducing Potential Hemilability into “Click” Triazoles and Triazolylidenes: Synthesis and Characterization of d⁶‐Metal Complexes and Oxidation Catalysis

Metal Complexes of Click-Derived Triazoles and Mesoionic Carbenes: Electron Transfer, Photochemistry, Magnetic Bistability, and Catalysis

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A linear Cu (II) coordination polymer based on a simple click chelator

Cited by 11 publications

References 28 publications

A rare polymeric azido-bridged copper(II) chain with a pentameric repeating unit: Synthesis, structure and magnetic properties

A rare polymeric azido-bridged copper(II) chain with a pentameric repeating unit: Synthesis, structure and magnetic properties

Introducing Potential Hemilability into “Click” Triazoles and Triazolylidenes: Synthesis and Characterization of d6‐Metal Complexes and Oxidation Catalysis

Metal Complexes of Click-Derived Triazoles and Mesoionic Carbenes: Electron Transfer, Photochemistry, Magnetic Bistability, and Catalysis

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Introducing Potential Hemilability into “Click” Triazoles and Triazolylidenes: Synthesis and Characterization of d⁶‐Metal Complexes and Oxidation Catalysis