A low-cost biosorbent-based coating for the highly sensitive determination of organochlorine pesticides by solid-phase microextraction and gas chromatography-electron capture detection

Carmo, Sângela Nascimento do; Merib, Josias; Dias, Adriana Neves; Stolberg, Joni; Budziak, Dilma; Carasek, Eduardo

doi:10.1016/j.chroma.2017.10.018

Cited by 45 publications

(25 citation statements)

References 41 publications

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“…Another lignocellulosic material was reported in 2017 as a green extraction phase for SPME [20]. The material, called bract, is the non-developed seeds obtained from the tree Araucaria angustifolia (Bert) O. Kuntze, a conifer found in the south and southeast of Brazil and in eastern Argentina.…”

Section: Bract As a Biosorbentmentioning

confidence: 99%

“…The characterization of bract fiber carried out by thermogravimetric analysis (TGA), SEM and FTIR showed that the fiber offers satisfactory thermal stability with no decomposition observed up to 260 °C. SEM micrographs presented a highly porous and rough morphology and a film thickness of approximately 60 µ m [20]. Like cork, bract is also a lignocellulosic material.…”

Section: Bract As a Biosorbentmentioning

confidence: 99%

“…Both materials are similar; however, the cork powder presents a better attachment to the nitinol wire, so it is easier to handle. Bract has been used as an environmentally friendly and low-cost biosorbent coating for SPME for the determination of OCPs in river and lake water [20] and PAH's in river water [21] ( Table 1). The characterization of bract fiber carried out by thermogravimetric analysis (TGA), SEM and FTIR showed that the fiber offers satisfactory thermal stability with no decomposition observed up to 260 • C. SEM micrographs presented a highly porous and rough morphology and a film thickness of approximately 60 µm [20].…”

Section: Bract As a Biosorbentmentioning

confidence: 99%

“…(2A) Scheme of the preparation of SPME fibers and (2B) SEM micrographs obtained for bract fiber (a) magnification of 1500× (b) magnification of 3000× and (c) a cross-section of the proposed fiber at magnification of 300×. Reproduced with permission from[20], Copyright Elsevier, 2017. Scheme of the biobased bar-adsorptive microextraction (BAµE) procedure to determine hexanal and heptanal in human urine by HPLC-DAD.…”

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Alternative Green Extraction Phases Applied to Microextraction Techniques for Organic Compound Determination

et al. 2019

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The use of green extraction phases has gained much attention in different fields of study, including in sample preparation for the determination of organic compounds by chromatography techniques. Green extraction phases are considered as an alternative to conventional phases due to several advantages such as non-toxicity, biodegradability, low cost and ease of preparation. In addition, the use of greener extraction phases reinforces the environmentally-friendly features of microextraction techniques. Thus, this work presents a review about new materials that have been used in extraction phases applied to liquid and sorbent-based microextractions of organic compounds in different matrices.

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Section: Bract As a Biosorbentmentioning

confidence: 99%

Section: Bract As a Biosorbentmentioning

confidence: 99%

Section: Bract As a Biosorbentmentioning

confidence: 99%

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confidence: 99%

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Alternative Green Extraction Phases Applied to Microextraction Techniques for Organic Compound Determination

et al. 2019

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“…Many of these biosorbents can be found in the environment and consist of macromolecules with different functional groups that can interact with different types of analytes. Our research group has previously used natural sorbents for the determination of organic contaminants using SPME [17,18]. Diatomaceous earth is of particular interest as a new biosorbent since it is discarded in large scale as a waste from breweries, where it is used for the clarification and filtration of organic materials and beers [19].…”

Section: Introductionmentioning

confidence: 99%

A Low-Cost Approach Using Diatomaceous Earth Biosorbent as Alternative SPME Coating for the Determination of PAHs in Water Samples by GC-MS

et al. 2018

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In this study, the use of recycled diatomaceous earth as the extraction phase in solid phase microextraction (SPME) technique for the determination of polycyclic aromatic hydrocarbons (PAHs) in river water samples, with separation/detection performed by gas chromatography-mass spectrometry (GC-MS), is proposed. The optimized extraction conditions are extraction time 70 min at 80 °C with no addition of salt. The limits of quantification were close to 0.5 μg L−1 with RSD values lower than 25% (n = 3). The linear working range was 0.5 μg L−1 to 25 μg L−1 for all analytes. The method was applied to samples collected from the Itajaí River (Santa Catarina, Brazil) and the RSD values for repeatability and reproducibility were lower than 15% and 17%, respectively. The efficiency of the recycled diatomaceous earth fiber was compared with that of commercial fibers and good results were obtained, confirming that this is a promising option to use as the extraction phase in SPME.

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Determination of pesticides residues in vegetable and fruit samples by solid‐phase microextraction with a covalent organic framework as the fiber coating coupled with gas chromatography and electron capture detection

Wang

Zhou

Zang

et al. 2018

J of Separation Science

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In this study, a covalent organic framework designated as TpPaNO was synthesized by a mechanochemical grinding method and then coated on stainless steel wire by a sol-gel technique to prepare a solid-phase microextraction fiber. The TpPaNO fiber based solid-phase microextraction coupled with gas chromatography-electron capture detection was applied to determine the residues of 11 pesticides (trlfuralln, dicofol, α-endosulfan, 1-chloro-4-[2,2-dichloro-1-(4-chlorophenyl)ethenyl]benzene, nitrofen, β-endosulfan, 1-chloro-4-[2,2-dichloro-1-(4-chlorophenyl)ethyl]benzene, 1,1,1-trichloro-2,2-bis(4-chlorophenyl)ethane, bifenthrin, permethrin and fenvalerate) in vegetable and fruit samples. The effects of extraction time, extraction temperature, sample pH, stirring rate and desorption temperature on the extraction efficiency were investigated. Under the optimized conditions, the limits of detection for the eleven pesticides were in the range of 0.04-0.25 μg/kg. The recoveries of the eleven pesticides in the vegetable and fruit samples were 81.5-111% with the relative standard deviations less than 11.2%.

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A low-cost biosorbent-based coating for the highly sensitive determination of organochlorine pesticides by solid-phase microextraction and gas chromatography-electron capture detection

Cited by 45 publications

References 41 publications

Alternative Green Extraction Phases Applied to Microextraction Techniques for Organic Compound Determination

Alternative Green Extraction Phases Applied to Microextraction Techniques for Organic Compound Determination

A Low-Cost Approach Using Diatomaceous Earth Biosorbent as Alternative SPME Coating for the Determination of PAHs in Water Samples by GC-MS

Determination of pesticides residues in vegetable and fruit samples by solid‐phase microextraction with a covalent organic framework as the fiber coating coupled with gas chromatography and electron capture detection

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