A low sensitivity energetic cocrystal of ammonium pentazolate

Xu, Yuangang; Li, Dongxue; Wang, Pengcheng; Lin, Qiuhan; Ding, Lei; Hou, Tianyang; Yuan, Yuan; Lu, Ming

doi:10.1080/07370652.2021.1928795

Cited by 8 publications

(3 citation statements)

References 32 publications

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“…The cocrystals are formed mainly by the N—H···N and N—H···Cl hydrogen bonds, and π-π interactions. Due to this crystal structure, the ECC is found to have a higher decomposition temperature, lower sensitivity, and improved detonation performance as compared to the individual coformers [ 70 ]. In addition to this, there several cocrystals that have been reported in 2021 and 2022 which are made up of CL-20, BTF, and HMX.…”

Section: New Energetic Cocrystalsmentioning

confidence: 99%

Recent Progress on Synthesis, Characterization, and Performance of Energetic Cocrystals: A Review

Sultan

Haq

et al. 2022

Molecules

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In the niche area of energetic materials, a balance between energy and safety is extremely important. To address this “energy–safety contradiction”, energetic cocrystals have been introduced. The investigation of the synthesis methods, characteristics, and efficacy of energetic cocrystals is of the utmost importance for optimizing their design and development. This review covers (i) various synthesis methods for energetic cocrystals; (ii) discusses their characteristics such as structural properties, detonation performance, sensitivity analysis, thermal properties, and morphology mapping, along with other properties such as oxygen balance, solubility, and fluorescence; and (iii) performance with respect to energy contents (detonation velocity and pressure) and sensitivity. This is followed by concluding remarks together with future perspectives.

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Section: New Energetic Cocrystalsmentioning

confidence: 99%

Recent Progress on Synthesis, Characterization, and Performance of Energetic Cocrystals: A Review

Sultan

Haq

et al. 2022

Molecules

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“…The structure, thermal behavior, sensitivity, and detonation properties of NH 4 N 5 ·1/6NH 4 Cl were studied. DSC-TG-MS combined techniques showed that the cocrystal has better thermal stability than NH 4 N 5 , exhibits low impact and friction sensitivity, and largely reduces the mechanical sensitivity [ 26 ].…”

Section: Applications To Complexes and Compoundsmentioning

confidence: 99%

On-Line Thermally Induced Evolved Gas Analysis: An Update—Part 1: EGA-MS

et al. 2022

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Advances in on-line thermally induced evolved gas analysis (OLTI-EGA) have been systematically reported by our group to update their applications in several different fields and to provide useful starting references. The importance of an accurate interpretation of the thermally-induced reaction mechanism which involves the formation of gaseous species is necessary to obtain the characterization of the evolved products. In this review, applications of Evolved Gas Analysis (EGA) performed by on-line coupling heating devices to mass spectrometry (EGA-MS), are reported. Reported references clearly demonstrate that the characterization of the nature of volatile products released by a substance subjected to a controlled temperature program allows us to prove a supposed reaction or composition, either under isothermal or under heating conditions. Selected 2019, 2020, and 2021 references are collected and briefly described in this review.

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“…One year later, HTATOTN 5 /TATOT 11 and NH 4 N 5 /1/6NH 4 Cl (ref. 12) were then successfully synthesized (Fig. 1).…”

mentioning

confidence: 99%