The vertical emission profile of the O2 (a1Δg) airglow at 1.27 μm has been measured during the evening twilight near the equator (Alcântara, Brazil; 2.5°S, 44.2°W) using a rocket‐borne infrared photometer. The profile is used to derive the vertical distribution of ozone between 60 and 86 km. The ozone profile shows a minimum concentration at 77 km and a secondary maximum of 1.34 × 108 cm−3 at 82 km. The height of the secondary maximum is lower than observed at midlatitudes, and the 77‐km minimum is sharper than that which has been observed at low latitudes by satellite measurements.