In order to improve decision-making efficiency about emergency event, this paper proposes a novel concept, i.e., Agile-Delphi Method, which is an integration of agile decision and Delphi Method implicating that the decision-makers instantly deliver, respond, treat, and utilize information via Delphi process while conducting group decision-making about emergency event. The paper details the mechanism of group decision-making about emergency event based on network technology and Agile-Delphi Method. Finally, the paper conducts an empiric analysis taking the ''111 event'', i.e., the liquid ammonia spill event happened on November 1, 2006 in a phosphorus chemical company in China, as an example.