A molecular aluminium fulleride

Lawrence, Samuel R.; Rüffer, Tobias; Stasch, Andreas; Kretschmer, Robert

doi:10.1039/d3cc01609a

Chem. Commun.

2023

DOI: 10.1039/d3cc01609a

|View full text |Cite

A molecular aluminium fulleride

Samuel R. Lawrence

Tobias Rüffer

Andreas Stasch

et al.

Abstract: Go-Al! low valent aluminium scores a Hat-trick by converting C60 to a tri-substituted molecular aluminium fulleride.

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

Publication Types

Select...

Article1

Relationship

Self Cite0

Independent1

Authors

Journals

Cited by 1 publication

References 39 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

A Well‐Defined Magnesium Complex of C₇₀⁶⁻

Lawrence,

Demidov,

André Ohlin

et al. 2024

Chemistry A European J

View full text Add to dashboard Cite

Controlling and understanding charge state and metal coordination in carbon nanomaterials is crucial to harnessing their unique properties. Here we describe the synthesis of the well‐defined fulleride complex [{(Mesnacnac)Mg}6C70], 2, (Mesnacnac) = HC(MeCNMes)2, Mes = 2,4,6‐Me3C6H2, from the reaction of the β‐diketiminate magnesium(I) complex [{(Mesnacnac)Mg}2] with C70 in aromatic solvents. The molecular structure of complex 2 was determined, providing the first high‐quality structural study of a complex with the C706‐ ion. In combination with solution state NMR spectroscopic and DFT computational studies, the changes in geometry and charge distribution in the various atom and bond types of the fulleride unit were investigated. Additionally, the influence of the (Mesnacnac)Mg+ cations on the global and local fulleride coordination environment was examined.

show abstract

A Well‐Defined Magnesium Complex of C₇₀⁶⁻

Lawrence,

Demidov,

André Ohlin

et al. 2024

Chemistry A European J

View full text Add to dashboard Cite

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

A molecular aluminium fulleride

Abstract: Go-Al! low valent aluminium scores a Hat-trick by converting C60 to a tri-substituted molecular aluminium fulleride.

Cited by 1 publication

References 39 publications

A Well‐Defined Magnesium Complex of C₇₀⁶⁻

A Well‐Defined Magnesium Complex of C₇₀⁶⁻

Contact Info

Product

Resources

About

A molecular aluminium fulleride

Abstract: Go-Al! low valent aluminium scores a Hat-trick by converting C60 to a tri-substituted molecular aluminium fulleride.

Cited by 1 publication

References 39 publications

A Well‐Defined Magnesium Complex of C706−

A Well‐Defined Magnesium Complex of C706−

Contact Info

Product

Resources

About

A Well‐Defined Magnesium Complex of C₇₀⁶⁻

A Well‐Defined Magnesium Complex of C₇₀⁶⁻