2016
DOI: 10.1016/j.inoche.2016.05.017
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A molecular layer “fabric” with orthogonally woven coordination polymer chains

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Cited by 8 publications
(4 citation statements)
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“…Strictly, rhr does not belong as the other condition of straight lines is required to determine the coordinates ( x , x , 0) of intersections. Besides the nbo pattern described here, the 2-periodic sql net also is observed in all the coordination polymers that show warp-and-woof entanglements. …”
Section: Invariant Line Setssupporting
confidence: 51%
See 1 more Smart Citation
“…Strictly, rhr does not belong as the other condition of straight lines is required to determine the coordinates ( x , x , 0) of intersections. Besides the nbo pattern described here, the 2-periodic sql net also is observed in all the coordination polymers that show warp-and-woof entanglements. …”
Section: Invariant Line Setssupporting
confidence: 51%
“…This structure is a rare example of helices with axes in two directions and thus not parallel to principal symmetry axes. The rod packing is the invariant four-layer tetragonal structure …”
Section: Structure Descriptionsmentioning
confidence: 99%
“…Similarly, [Mn­(salen)­Au­(CN) 2 ] 4 (H 2 O) (salen = N , N ′-ethylene-bis­(salicylideneaminato), [Mn­(acacen)­Ag­(CN) 2 ] (acacen = N , N ′-ethylene-bis­(acetylacetonylideneiminate)) and [Zn­(bac) 2 (bpp)]·1.5H 2 O (bac = 1-benzoylacetone) display identical warp-and-woof type cloth-like array formed by two almost orthogonal 1D helical chains with different chirality (Figure d,e). , Later, LaDuca et al . also reported an identical 1D CP [Cu­(ox)­(dpa)­(H 2 O)] (ox = oxalate; dpa = 4,4′-dipyridylamine) . Complex [Pb­(bpe)­(CH 3 COO)­(CF 3 COO)] with 1D spiral chains also features similar structure in which the chains are almost parallel, however, perpendicular with respect to CC bond (Figure f) …”
Section: Different Entanglementsmentioning
confidence: 99%
“…Metal oxalate salts are ubiquitous in nature (Baran, 2014) and are also of great interest to synthetic chemists and materials scientists because they often display unusual magnetic and conductive properties (Nenwa et al, 2015;Robinson et al, 2015;Zhang et al, 2012;Clemente-Leó n et al, 2011;Gruselle et al, 2006). Other areas of study for metal oxalates include, but are not limited to, metallogels (Feldner et al, 2016), coordination polymers and networks (Guo et al, 2016;Mizzi & LaDuca, 2016;Yeşilel et al, 2010), and precursors for nanomaterials and metallic inks (Yadav et al, 2013;Cheng et al, 2016). The properties of metal oxalates are often tuned by using a combination of different cations.…”
Section: Chemical Contextmentioning
confidence: 99%