A new microporous structure constructed by a lanthanide-carboxylate coordination polymer

Synthesis, Crystal Structure, Spectroscopic and Thermal Investigations of a Novel 2D Sodium(I) Coordination Polymer Based on 2-Aminoterephthalic Ligand

“…The structural formula of the neutral H 2 atpt is shown in Scheme 1. In fact, many studies about atpt were focused on lanthanide and transition metal coordination polymers [15][16][17][18][19][20][21][22][23][24]. In the structure of these complexes only carboxylate groups of atpt ligand take part in metal bonding.…”

A family of lanthanide-containing molecular open frameworks with high porosity: [Ln(abdc)(Habdc), nH2O]∞ with Ln=La–Eu and 8⩽n⩽11

“…Among the benzene-poly-carboxylate based compounds, the terephthalate containing ones revealed to be particularly interesting [23,28,31]. On the other hand, the amino-substituted benzenepoly-carboxylate ligands tend to promote 3D molecular structure when associated with lanthanide ions [27,[41][42][43][44][45][46][47]. We have thus undertaken the study of the amino-terephthalate/Ln(III) system in water (Scheme 1).…”

Synthesis and Characterization of a New Three-Dimensional Lanthanide Carboxyphosphonate: Ln4(H2O)7[O2C−C5H10N−CH2-PO3]4(H2O)5

“…However, most of the lanthanide-based hybrid solids discovered up to now are coordination polymers in which the metallic moieties are either single polyhedra or isolated small clusters. Some 3D coordination polymers have been reported using dicarboxylates, − sulfonates, and bipyridine . This leads to a drastic decrease in their performance and/or their thermal stability required for applicable properties.…”