A new Mn(Ⅱ)-based metal-organic framework: synthesis, characterization, ferrimagnetic behavior and catalytic conversion of CO2 to cyclic carbonates

Gu, Rui-Ying; Liu, Shuang; Zhang, Wen-Chao; Li, Lei-Lei; Zhu, Jia-Bao; Chen, Ming-Rui; Zhou, Hang

doi:10.1016/j.ica.2024.121978

Inorganica Chimica Acta

2024

DOI: 10.1016/j.ica.2024.121978

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A new Mn(Ⅱ)-based metal-organic framework: synthesis, characterization, ferrimagnetic behavior and catalytic conversion of CO2 to cyclic carbonates

Rui-Ying Gu,

Shuang Liu,

Wen-Chao Zhang

et al.

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A novel Eu8 cluster for efficiently catalyzing CO2 cycloaddition and Knoevenagel condensation

Zhong,

Tang,

Jia

et al. 2025

Journal of Molecular Structure

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A novel Eu8 cluster for efficiently catalyzing CO2 cycloaddition and Knoevenagel condensation

Zhong,

Tang,

Jia

et al. 2025

Journal of Molecular Structure

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A doubly Phenoxyacetate-bridged dinuclear manganese(II) complex with 1,10-Phenanthroline: Synthesis, 1-D supramolecular structure, Hirshfeld surface analysis, magnetic and theoretical studies

Ajibola,

Cubillán,

Coba-Jiménez

et al. 2025

Polyhedron

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Effects of Mixed Metal Oxide Catalysts on the Synthesis of Cyclic Carbonates from Epoxides under Atmospheric CO₂ Pressure

Vergara-Arenas,

Nicholls,

Negrón-Silva

et al. 2024

ACS Omega

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One use of CO 2 as a starting material in organic transformations is in the synthesis of cyclic carbonates and polycarbonates. Due to the low reactivity of CO 2 , this transformation must be carried out in the presence of an efficient catalyst. Although several catalytic systems have been developed in the past decade, reducing the CO 2 pressure at which the reaction is carried out remains one of the main challenges of the process. In this context, in the present work, we describe the catalytic activity of mixed metal oxides in the synthesis of cyclic carbonates from CO 2 (1 atm) and epoxides at 70 °C. Using these materials as catalysts represents significant benefits since they are very stable, cost-effective, and can be reused in several reaction cycles.

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A new Mn(Ⅱ)-based metal-organic framework: synthesis, characterization, ferrimagnetic behavior and catalytic conversion of CO2 to cyclic carbonates

Cited by 3 publications

References 37 publications

A novel Eu8 cluster for efficiently catalyzing CO2 cycloaddition and Knoevenagel condensation

A novel Eu8 cluster for efficiently catalyzing CO2 cycloaddition and Knoevenagel condensation

A doubly Phenoxyacetate-bridged dinuclear manganese(II) complex with 1,10-Phenanthroline: Synthesis, 1-D supramolecular structure, Hirshfeld surface analysis, magnetic and theoretical studies

Effects of Mixed Metal Oxide Catalysts on the Synthesis of Cyclic Carbonates from Epoxides under Atmospheric CO₂ Pressure

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A new Mn(Ⅱ)-based metal-organic framework: synthesis, characterization, ferrimagnetic behavior and catalytic conversion of CO2 to cyclic carbonates

Cited by 3 publications

References 37 publications

A novel Eu8 cluster for efficiently catalyzing CO2 cycloaddition and Knoevenagel condensation

A novel Eu8 cluster for efficiently catalyzing CO2 cycloaddition and Knoevenagel condensation

A doubly Phenoxyacetate-bridged dinuclear manganese(II) complex with 1,10-Phenanthroline: Synthesis, 1-D supramolecular structure, Hirshfeld surface analysis, magnetic and theoretical studies

Effects of Mixed Metal Oxide Catalysts on the Synthesis of Cyclic Carbonates from Epoxides under Atmospheric CO2 Pressure

Contact Info

Product

Resources

About

Effects of Mixed Metal Oxide Catalysts on the Synthesis of Cyclic Carbonates from Epoxides under Atmospheric CO₂ Pressure