A New Paramagnetic Pd(dmit)2 Salt: Tris(2,2′-Bipyridine)Nickel(II) Bis(1,3-Dithiole-2-Thione-4,5-Dithiolato)Palladate(II) Mono-Acetonitrile; [Ni(bpy)3][Pd(dmit)2]·CH3CN

Preparation and characterization of a novel hybrid magnetic semiconductor containing rare, one-dimensional mixed-iodide/chloride anion of lead(II)

“…The Ni-N bond lengths have a range of 2.079(7)-2.094(7) Å ; the two N atoms from each bipy ligand with the Ni atom form a five-membered chelate ring with the bond angle 78.5(3)-79.7(3)1. They compare well with that in compound [Ni(bipy) 3 ][Pd(dmit) 2 ] Á CH 3 CN with Ni-N ¼ 2.064(3)-2.113 (3) Å and N-Ni-N ¼ 78.2(1)À79.2(1)1 [14]. The Ni?Ni distance is 8.3421(17) Å .…”