A new SF5-containing solid ether-bis(β-pentafluorothio-β-fluorosulfonyl-ethyl)ether

Winter, R.; Gard, Gary L.; Mews, R.; Noltemeyer, M.

doi:10.1016/s0022-1139(98)00091-8

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Chemistry Of Aliphatic Sf5 Compounds1

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1998

2022

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Cited by 3 publications

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“…One of the more versatile SF 5 -substituted unsaturated compounds is SF 5 -ketene. Ketenes have been used to prepare a variety of organic compounds ranging from carboxylic acid derivatives, ,,, ethers, and alkylidenesulfur fluorides. , Additionally, SF 5 -ketene has been observed to dimerize upon heating ,,, and in the presence of a metal fluoride (e.g., KF or CsF) polymerizes to form a rubbery solid. , Scheme illustrates the various reactions of SF 5 ketenes.…”

Section: Chemistry Of Aliphatic Sf5 Compoundsmentioning

confidence: 99%

Preparation and Utility of Organic Pentafluorosulfanyl-Containing Compounds

2014

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Scheme 113. Preparation of SF 5 -Containing Arylboronic Acids and Use in Conia−Ene Cyclizations a a Reagents and conditions: (a) i-PrMgBr (1.2 equiv), B(OMe) 3 THF, −78 to 25 °C (65%); (b) 429, PhMe (3−73%). Scheme 114. Preparation of SF 5 -Containing Binaphthyl Compounds a a Reagents and conditions: (a) 428, Pd(PPh 3 ) 4 (10%), K 2 CO 3 , DMF; (b) BBr 3 (75%); (c) POCl 3 ; (d) H 2 O. Scheme 115. Asymmetric Protonation via SF 5 -Containing Acid 436 a a Reagents and conditions: (a) 436 (catalytic).

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