A New Structure Type of the Ternary Sulfide Eu1.3Nb1.9S5

Khasanova, Nellie R.; Tendeloo, Gustaaf Van; Lebedev, Oleg I.; Amelinckx, S.; Grippa, A.Yu.; Abakumov, Artem M.; Istomin, S.Ya.; D'yachenko, O.G.; Antipov, Evgeny V.

doi:10.1006/jssc.2001.9501

Search citation statements

Order By: Relevance

Paper Sections

Select...

Methods1

Discussion1

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2003

2020

Publication Types

Select...

Article3

Book1

Relationship

Self Cite0

Independent4

Authors

Journals

Cited by 4 publications

(2 citation statements)

References 14 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Within the same batch, analyses of small black platelets with a hexagonal shape gave the composition (at. %, mean of 10 spot analyses): Eu 24.1(1), Nb 15.9(1), S 60.0(6), which, on the basis of 22 S atoms, led to the formula Nb 8.82 Eu 5.85 S 22 , close to the structural formula of the commensurate composite compound Nb 8 Eu 6 S 22 recently described by Khasanova et al…”

Section: Methodssupporting

confidence: 71%

“…In both misfit compounds (EuS) 1.173 NbS 2 and [(EuS) 1.5 ] 1.15 NbS 2 the mixed valence state of europium allows a charge transfer of about 0.6 electron per niobium atoms from the [EuS] to the [NbS 2 ] slabs which is sufficient to stabilize the structure. It is likely that such a situation (mixed valence and charge transfer) is also prevalent in the recently discovered composite compound [Nb 7 S 14 ][Nb(Eu 3 S 4 ) 2 ] where a Nb(Eu 3 S 4 ) 2 layer alternates with a NbS 2 layer, although the authors envisage only a divalent state for Eu …”

Section: Discussionmentioning

confidence: 99%

See 1 more Smart Citation