A New Synthesis of the Chromium Hexacarbonyl

Natta, G.; Ercoli, Raffaele; Calderazzo, Fausto; Rabizzoni, A.

doi:10.1021/ja01570a092

Cited by 31 publications

(19 citation statements)

References 1 publication

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Mo 2 (g 6 :g 6 -C 6 H 5 -C 6 H 5 )(CO) 6 The binuclear chromium derivative Cr 2 (g 6 :g 6 -C 6 H 5 -C 6 H 5 )(CO) 6 was originally obtained by reacting Cr(CO) 6 with melted diphenyl [37] or in a THF/Bu 2 O mixture [6c]. The structure consists of a diphenyl ligand bridging two {Cr(CO) 3 } fragments in a trans arrangement [29].…”

Section: Mononuclear Compoundsmentioning

confidence: 99%

Synthesis, electrochemistry, and crystal and molecular structures of some molybdenum(0) arene derivatives with fluorinated and phenyl-substituted arene ligands

Abednatanzi¹,

Calderazzo²,

Englert

et al. 2004

Journal of Organometallic Chemistry

View full text Add to dashboard Cite

Section: Mononuclear Compoundsmentioning

confidence: 99%

Synthesis, electrochemistry, and crystal and molecular structures of some molybdenum(0) arene derivatives with fluorinated and phenyl-substituted arene ligands

Abednatanzi¹,

Calderazzo²,

Englert

et al. 2004

Journal of Organometallic Chemistry

View full text Add to dashboard Cite

“…, [Cr(C0)3(1,2,3,4-tetrahydronaphthalene)] (3) [36] [37], and [Cr(CO),(o-xylene)] (4) were prepared via literature procedures either by thermolysis of Cr(CO), [39] or by areue exchange in [Cr(C0)3(naphthalene)] [40].…”

Section: Experimental Partmentioning

confidence: 99%

Addition of Carbon Nucleophiles to Tricarbonylchromium Complexes of 1,2‐Dihydrocyclobutabenzene, Indane, 1,2,3,4‐Tetrahydronaphtbalene and ortho‐Xylene

Kündig¹,

Grivet²,

Wenger³

et al. 1991

Helvetica Chimica Acta

View full text Add to dashboard Cite

show abstract

“…Following this initial discovery, several additional routes to benzenechromium tricarbonyl and related complexes were developed, the most con venient of which involves the simple refluxing of the metal carbonyl and arene with concurrent loss of carbon monoxide (96,97,184,186,187 on the reactivity of the arene ligand might be expected to be quite pro nounced, and already a number of notable developments have been described in the literature. Thus, while benzene-chromium tricarbonyl undergoes Friedel-Crafts acylation readily (17,81,216), nucleophilic-type reactions such as the facile conversion of fluorobenzene-chromium tri carbonyl (XXVIII) to anisole-chromium tricarbonyl (XXIX) also occur in high yield (17,186,187).…”

Section: Cr(c0)6 + (C6h6)2 Crmentioning

confidence: 99%

“…Recently, Pettit and co-workers (184) have shown that the relative rate of solvolysis of benzyl chloride-chromium tricarbonyl is about a million times faster than for uncomplexed benzyl chloride under analogous SNI conditions. The area of carbonium ion formation and stabilization in arene-metal systems thus represents another fertile field for future investigation.…”

Section: Cr(c0)6 + (C6h6)2 Crmentioning

confidence: 99%

The History and Development of Organotransition Metal Chemistry

Rausch

1967

Werner Centennial

View full text Add to dashboard Cite

Organotransition metal compounds have been known for over a century, but it has been only during the past 15 years that most of the major advances in this area have been made. Organotransition metal compounds consist of organic molecules or ligands coordinated to transition metals by one or more carbon atoms. In the present sur vey, the formation, properties, structure, and reactions of various classes of these substances are discussed. Empha sis has been placed on important discoveries and theories that have stimulated the rapid progress of organotransition metal chemistry. Pertinent reviews on various aspects of this subject have also been cited./^\rganometallic compounds containing neutral, unsaturated organic molecules coordinated to certain transition metals were known long before the advent of Werner's theories on coordination compounds. Until about 1950, however, this aspect of coordination chemistry remained fal low, and the structure and bonding of the compounds known at that time were quite perplexing. The discovery of ferrocene and the development of a rational theory of bonding in olefin-transition metal complexes in the early 1950's prompted a vigorous research effort around the world that has attracted the attention of organic chemists, inorganic chemists, crystallographers, and scientists of many allied disciplines. Research in organo transition metal chemistry presently is proceeding at a very rapid rate, and the synthesis and properties of seemingly unlimited new types of "organometallic, T complexes" represent an important frontier in coordina tion chemistry.The purpose of the present survey is twofold. Firstly, because the Werner Symposium is partly historical, some of the more important dis coveries and theories that have led to the present high level of interest in 486 Downloaded by UNIV OF NORTH CAROLINA on February 18, 2015 |

show abstract

A New Synthesis of the Chromium Hexacarbonyl

Cited by 31 publications

References 1 publication

Synthesis, electrochemistry, and crystal and molecular structures of some molybdenum(0) arene derivatives with fluorinated and phenyl-substituted arene ligands

Synthesis, electrochemistry, and crystal and molecular structures of some molybdenum(0) arene derivatives with fluorinated and phenyl-substituted arene ligands

Addition of Carbon Nucleophiles to Tricarbonylchromium Complexes of 1,2‐Dihydrocyclobutabenzene, Indane, 1,2,3,4‐Tetrahydronaphtbalene and ortho‐Xylene

The History and Development of Organotransition Metal Chemistry

Contact Info

Product

Resources

About