A nitrosyl iron complex with 3.4-dichlorothiophenolyl ligands: synthesis, structures and its reactions with targets – carriers of nitrogen oxide (NO) in vivo

Abstract

In this work, a new binuclear nitrosyl complex with 3.4-dichlorothiophenolyl ligands [Fe2(SC6H3Cl2)2(NO)4] has been synthesized. Nitrosyl iron complexes (NICs) are a form of storage and delivery of NO in the...

Synthesis of a tetranitrosyl iron complex with unique structure and properties as an inhibitor of phosphodiesterases

“…In addition, we have previously shown that binuclear tetranitrosyl iron complexes, namely, the complex with 3,4-dichlorothiophenol 69 and other aromatic and aliphatic 70 ligands, when dissolved in DMSO, decomposed to yield mononuclear products. We have also shown that DMSO in both binuclear 69 and mononuclear complexes 27,71 can exert significant influence on the mechanism of their further decomposition in solutions.…”