A novel glucose sensor based on immobilization of glucose oxidase on the chitosan-coated Fe 3 O 4 nanoparticles and the luminol–H 2 O 2 –gold nanoparticle chemiluminescence detection system

Chaichi, Mohammad Javad; Ehsani, Mahjoobeh

doi:10.1016/j.snb.2015.09.125

Cited by 130 publications

(46 citation statements)

References 55 publications

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“…It has been reported that Vc at high concentrations can interfere with the sensor response, probably because it easily reduces H 2 O 2 produced from the enzymatic reaction. 51 In our case, however, it did not have any interference with the CL detection of glucose at the concentration of 0.15 mM over the upper limit of normal concentration range (34-79 mM in human blood…”

Section: Assays Of H 2 O 2 and Glucose On The Presented Platformcontrasting

confidence: 52%

Facile and sensitive chemiluminescence detection of H₂O₂ and glucose by a gravity/capillary flow and cloth-based low-cost platform

Wang

Liu

et al. 2017

RSC Adv.

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This paper describes the development of a cloth-based CL strategy that can quantify H 2 O 2 or glucose in a low-cost, easy-to-use, rapid and sensitive manner. Wax screen-printing is applied to fabricate the ultralow-cost cloth-based devices, and thus the as-prepared sensors have a very low cost (about $0.01 per assay). Moreover, an inexpensive CCD camera is used to image the light from the gravity/capillary flow-triggered enzyme-catalysed oxidation of luminol by H 2 O 2 . Under optimized conditions, the developed CL platform can fulfill the determination of H 2 O 2 , with a linear range of 0.01-10 mM and a detection limit of 9.07 mM. Similarly, glucose can be detected in the range of 0.01-10 mM, with a detection limit of 9.74 mM. Additionally, the RSDs of these two assays are 3.36%, 3.66% and 2.64% for 0.01, 0.1 and 5 mM H 2 O 2 , and 3.01%, 2.80% and 3.68% for 0.1, 1 and 5 mM glucose, respectively.Moreover, the devices can maintain $95% of their initial response for three weeks, and tolerate a series of interfering species at reasonable concentrations. Therefore, the proposed platform has an acceptable sensitivity, linear range, reproducibility and stability. Finally, this platform is successfully applied to the detection of H 2 O 2 in milk and glucose in human serum.

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Section: Assays Of H 2 O 2 and Glucose On The Presented Platformcontrasting

confidence: 52%

Facile and sensitive chemiluminescence detection of H₂O₂ and glucose by a gravity/capillary flow and cloth-based low-cost platform

Wang

Liu

et al. 2017

RSC Adv.

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“…The easy and most convenient procedure of immobilization is the occlusion of carbon paste [11]. Polyphenol oxidase-based biosensors have been applied to the pharmaceutical analysis of phenolic drugs, including acetaminophen and acetyl salicylic acid analysis [12,13,14,15].…”

Section: Introductionmentioning

confidence: 99%

The Use of a Polyphenoloxidase Biosensor Obtained from the Fruit of Jurubeba (Solanum paniculatum L.) in the Determination of Paracetamol and Other Phenolic Drugs

et al. 2018

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The vegetable kingdom is a wide source of a diverse variety of enzymes with broad biotechnological applications. Among the main classes of plant enzymes, the polyphenol oxidases, which convert phenolic compounds to the related quinones, have been successfully used for biosensor development. The oxidation products from such enzymes can be electrochemically reduced, and the sensing is easily achieved by amperometric transducers. In this work, the polyphenoloxidases were extracted from jurubeba (Solanum paniculatum L.) fruits, and the extract was used to construct a carbon paste-based biosensor for pharmaceutical analysis and applications. The assay optimization was performed using a 0.1 mM catechol probe, taking into account the amount of enzymatic extract (50 or 200 μL) and the optimum pH (3.0 to 9.0) as well as some electrochemical differential pulse voltammetric (DPV) parameters (e.g., pulse amplitude, pulse range, pulse width, scan rate). Under optimized conditions, the biosensor was evaluated for the quantitative determination of acetaminophen, acetylsalicylic acid, methyldopa, and ascorbic acid. The best performance was obtained for acetaminophen, which responded linearly in the range between 5 and 245 μM (R = 0.9994), presenting a limit of detection of 3 μM and suitable repeatability ranging between 1.52% and 1.74% relative standard deviation (RSD).

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“…The mean particle size was 40 nm, and the magnetic Fe 3 O 4 particles physically aggregated. This could have been caused by the coercive force of the magnetic particles or the magnetic dipolar interactions between particles . The surface morphology of Fe 3 O 4 @CS is shown in Figure b.…”

Section: Resultsmentioning

confidence: 99%

Immobilization of Candida rugosa Lipase on Glutaraldehyde‐Activated Fe₃O₄@Chitosan as a Magnetically Separable Catalyst for Hydrolysis of Castor Oil

Zhao

Chen

et al. 2017

Euro J Lipid Sci & Tech

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In this study, the catalyzed hydrolysis of castor oil by Candida rugosa lipase (CRL) immobilized on glutaraldehyde‐activated magnetic Fe3O4@chitosan is investigated. Magnetic Fe3O4 is prepared by hydrothermal method and coated with chitosan (CS). Next, CRL is immobilized on Fe3O4@chitosan using glutaraldehyde as a cross‐linking reagent. The prepared Fe3O4@CS@CRL is confirmed by scanning electron microscopy (SEM), X‐ray powder diffraction (XRD), vibrating sample magnetometry (VSM), Fourier transform infrared (FTIR) spectroscopy, and thermogravimetric analysis (TGA). The response surface methodology (RSM) based on the Box–Behnken design is used to evaluate and optimize the hydrolysis reaction variables. The optimum reaction conditions for the hydrolysis of castor oil by the Fe3O4@CS@CRL heterogeneous catalyst are found to be a water/oil ratio of 1.60:1, pH of 7.05, reaction temperature of 34 °C, and lipase concentration of 3.27%; under these conditions, the hydrolysis conversion of castor oil reached 46.81%. Moreover, the immobilized lipase showed high stability with no appreciable loss in its activity after three consecutive cycles. Practical Applications: RSM is found to be a useful technique for optimizing hydrolysis of castor oil. The high conversion of the hydrolysis of castor oil indicates that the Fe3O4@CS@CRL have potential to be used in preparing ricinoleic acid from castor oil. Ricinoleic acid have the potential to be used in printing ink as a pigment and dye disperser, plasticizers, surfactants, lubricants, and other valuable products. Ricinoleic acid can be used in pigment and dye disperser in printing ink, sebacic acid, azelaic acid, heptaldehyde, plasticizers, surfactants, lubricants, and other valuable products. Hydrolysis of castor oil catalyzed by Candida rugosa lipase (CRL) immobilized on glutaraldehyde‐activated magnetic Fe3O4@chitosan is investigated. The response surface methodology (RSM) based on the Box–Behnken design is used to evaluate and optimize the hydrolysis reaction variables. Fe3O4@CS@CRL can be easily separated from the suspension using an external strong magnet. Fe3O4@CS@CRL have potential to be used in preparing ricinoleic acid from castor oil.

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A novel glucose sensor based on immobilization of glucose oxidase on the chitosan-coated Fe 3 O 4 nanoparticles and the luminol–H 2 O 2 –gold nanoparticle chemiluminescence detection system

Cited by 130 publications

References 55 publications

Facile and sensitive chemiluminescence detection of H₂O₂ and glucose by a gravity/capillary flow and cloth-based low-cost platform

Facile and sensitive chemiluminescence detection of H₂O₂ and glucose by a gravity/capillary flow and cloth-based low-cost platform

The Use of a Polyphenoloxidase Biosensor Obtained from the Fruit of Jurubeba (Solanum paniculatum L.) in the Determination of Paracetamol and Other Phenolic Drugs

Immobilization of Candida rugosa Lipase on Glutaraldehyde‐Activated Fe₃O₄@Chitosan as a Magnetically Separable Catalyst for Hydrolysis of Castor Oil

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A novel glucose sensor based on immobilization of glucose oxidase on the chitosan-coated Fe 3 O 4 nanoparticles and the luminol–H 2 O 2 –gold nanoparticle chemiluminescence detection system

Cited by 130 publications

References 55 publications

Facile and sensitive chemiluminescence detection of H2O2 and glucose by a gravity/capillary flow and cloth-based low-cost platform

Facile and sensitive chemiluminescence detection of H2O2 and glucose by a gravity/capillary flow and cloth-based low-cost platform

The Use of a Polyphenoloxidase Biosensor Obtained from the Fruit of Jurubeba (Solanum paniculatum L.) in the Determination of Paracetamol and Other Phenolic Drugs

Immobilization of Candida rugosa Lipase on Glutaraldehyde‐Activated Fe3O4@Chitosan as a Magnetically Separable Catalyst for Hydrolysis of Castor Oil

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Product

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Facile and sensitive chemiluminescence detection of H₂O₂ and glucose by a gravity/capillary flow and cloth-based low-cost platform

Facile and sensitive chemiluminescence detection of H₂O₂ and glucose by a gravity/capillary flow and cloth-based low-cost platform

Immobilization of Candida rugosa Lipase on Glutaraldehyde‐Activated Fe₃O₄@Chitosan as a Magnetically Separable Catalyst for Hydrolysis of Castor Oil