A novel metal–organic framework based on bismuth and trimesic acid: synthesis, structure and properties

Wang, Guanzhi; Liu, Yuanyuan; Huang, Baibiao; Qin, Xiaoyan; Zhang, Xiaoyang; Dai, Ying

doi:10.1039/c5dt03111g

Cited by 113 publications

(58 citation statements)

References 19 publications

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“…The X‐ray diffraction (XRD) pattern of Bi‐BTC is illustrated in Figure a. It can be found that the diffraction peaks of the as‐obtained sample agree well with the simulated result based on the single crystal structure, indicating the formation of Bi‐BTC. XRD measurements are performed to probe the crystal structures of pure Bi 2 S 3 , Bi 2 S 3 @RGO, and Bi 2 S 3 /C composites, as demonstrated in Figure b.…”

Section: Resultssupporting

confidence: 67%

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Bismuth Sulfide–Integrated Carbon Derived from Organic Ligands as a Superior Anode for Sodium Storage

et al. 2019

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Bismuth sulfide (Bi2S3) as a potential Na‐storage material relies upon its special layered structure and high volumetric capacity. However, the electrochemical activity of pure Bi2S3 is greatly limited during the sodiation/desodiation process. The integration of Bi2S3 with reduced graphene and a particular carbon is explored to acquire active composite anodes for sodium ion batteries (SIBs). This special carbon is based on trimesic acid (H3BTC) as a carbon source, which effectively prevents the aggregation of Bi2S3 particles in the synthesis process. Compared with other carbon sources, this type of carbon source is more likely to diffuse into the interior of the precursor hole. Hence, the Bi2S3/C indicates higher reversible capacities (368 and 314 mAh g−1 after 100 cycles and 200 cycles at 100 mA g−1) than bare Bi2S3 or Bi2S3@RGO. Thus, Bi2S3/C is considered as a prospective electrode material for rechargeable batteries.

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Section: Resultssupporting

confidence: 67%

“…Under magnetic stirring for complete dissolution, the obtained solution was poured into a 30 mL Teflon‐lined stainless steel autoclave. The autoclave was encapsulated and reacted at 120 °C for 45 h . Subsequently, the sample was collected by centrifugation, cleaned with methanol and DMF, and dried at 60 °C overnight.…”

Section: Methodsmentioning

confidence: 99%

Bismuth Sulfide–Integrated Carbon Derived from Organic Ligands as a Superior Anode for Sodium Storage

et al. 2019

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“…26 reported bismuth based MOFs (we were able to establish < 20). [30][31][32][33][34][35][36][37][38][39][40][41][42][43][44] Notably, zur Loye and coworkers have reported a number of Bi coordination polymers and their fluorescence properties using pyridine dicarboxylate as ligand. [44][45][46][47][48] Stock, Cheetham and co-workers have also reported a small variety of interesting Bi-MOFs.…”

mentioning

confidence: 99%

High-Performance Blue-Excitable Yellow Phosphor Obtained from an Activated Solvochromic Bismuth-Fluorophore Metal–Organic Framework

Deibert

Velasco

Liu

et al. 2016

Crystal Growth & Design

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We report the synthesis, structure, and photoluminescence properties of a new bismuth based luminescent metal−organic framework (LMOF). The framework is comprised of a 9-coordinated Bi 3+ building unit and 4′, 4‴, 4⁗′, 4⁗‴-(ethene-1,1,2,2-tetrayl)tetrakis([1,1′-biphenyl]-4carboxylic acid) (H 4 tcbpe) organic linker, which has strong yellow aggregation induced emission (AIE). The structure can be viewed as two interpenetrated 4,4-anionic nets that are stabilized by K + ions forming one-dimensional helical inorganic chains by connecting bismuth nodes through shared oxygen bonds. The as-made LMOF has a bluish emission centered at 459 nm with an internal quantum yield of 57% when excited at 360 nm. The emission properties of the LMOF were found to be highly solvochromic with respect to DMF. Upon partial solvent removal, the framework undergoes significant red-shifting to a greenish emission centered at 500 nm. Complete removal of DMF results in additional red-shifting fluorescence coupled with structural changes. The resulting material has strong blue-excitable (455 nm) yellow emission centered at 553 nm, with a quantum yield of 74%, which is maintained after heating in air for 5 days at 90 °C. This is the second highest quantum yield value for blue-excited yellow emission among all reported LMOFs.

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“…Considering the environmentally friendly character of bismuth element, the synthesis of MOFs based bismuth and H 3 BTC by a hydrothermal method and its photocatalytic performance was investigated, and its structure was characterized. Compared with the reported [Bi(BTC)(DMF)] · DMF(CH 3 OH) 2 (Bi–BTC) though dimethylformamide (DMF), the structure of the prepared Bi‐based MOFs is different from the one reported in the literature.…”

Section: Introductionmentioning

confidence: 70%

Synthesis, Characterization, and Photocatalytic Properties of Bismuth (III)-benzene-1,3,5-tricarboxylate

Ye¹,

Wei²,

Song³

et al. 2017

Z. Anorg. Allg. Chem.

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{[Bi(BTC)(H 2 O) 2 ]·H 2 O} n (H 3 BTC = 1,3,5-benzenetricarboxylic acid) was synthesized by an eco-friendly hydrothermal method and characterized by single-crystal X-ray diffraction, IR and UV/Vis spectroscopy, photoluminescence (PL), and thermogravimetric analyses. The complex featured a 3D metal-organic framework with Bi 2 secondary building units. In the complex, the central Bi 3+ is ninecoordinate, three central Bi atoms and three BTC 3anions are interconnected into a ring with the dimension of 7.95 ϫ 9.89 Å 2 . Moreover, the

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A novel metal–organic framework based on bismuth and trimesic acid: synthesis, structure and properties

Cited by 113 publications

References 19 publications

Bismuth Sulfide–Integrated Carbon Derived from Organic Ligands as a Superior Anode for Sodium Storage

Bismuth Sulfide–Integrated Carbon Derived from Organic Ligands as a Superior Anode for Sodium Storage

High-Performance Blue-Excitable Yellow Phosphor Obtained from an Activated Solvochromic Bismuth-Fluorophore Metal–Organic Framework

Synthesis, Characterization, and Photocatalytic Properties of Bismuth (III)-benzene-1,3,5-tricarboxylate

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