A Novel Migrative Addition Reaction of Hydrazines to the Diketone Derivatives of C₆₀.

Photochemical Orifice Expansion of a Cage-Opened C60 Derivative

“…The photoinduced C–C bond cleavage reactions are well-developed methods, as can be seen in photooxgenation and photochemical rearrangement (Figure ). Iwamatsu and co-workers reported thermal reactions using hydrazine and o -phenylenediamine, which undergo sequential C–C bond cleavage. The use of hypervalent iodine and secondary amines on fullerene-mixed peroxides have also been studied deeply by Gan and co-workers.…”